Английская Википедия:Carbide iodide

Материал из Онлайн справочника
Перейти к навигацииПерейти к поиску

Шаблон:Short description Carbide iodides are mixed anion compounds containing iodide and carbide anions. Many carbide iodides are cluster compounds, containing one, two or more carbon atoms in a core, surrounded by a layer of metal atoms, and encased in a shell of iodide ions. These ions may be shared between clusters to form chains, double chains or layers.

The metal in carbide iodides is most often a rare earth element. Similar formulas tend to have similar structures. Where R is a rare earth element: R12C6I17 contains chains of R6 octahedra with a C26− core and a shell of iodide. R4I5C contains similar chains, but with a single C4− carbide atom. Double chain structures with single carbon atom cores include R6I7C2 and R3I3C. Layers of joined octahedra include R2I2C2 with an ethanide C24− core; R2I2C and R2IC with one carbide per octahedron.[1]

Related compounds include carbide chlorides, and carbide bromides. Carbon may be substituted by hydrogen, boron or nitrogen in the core of cluster compounds.

This list does not include cyanides, carbonyls, cyanamides or carbido borates, where carbon has bonds to other non-metals. However, there are carbide iodides that also contain nitride, oxide or other halides.

List

Do not confuse Cl for chlorine, and CI for carbon and iodine.

formula system space group unit cell volume density comment reference
Sc2I3C triclinic PШаблон:Overbar a=10.793, b=10.803, c=13.959, α=87.8, β=73.04, γ=60.8 4,76 black [2]
Sc4C2I6 triclinic PШаблон:Overbar a=10.803 b=13.959 c=10.793 α=106.96° β=119.20° γ=87.80° Z=4 linear chains [3]
Sc6C2I11 triclinic PШаблон:Overbar a=10.046 b=14.152 c=9.030 α=104.36° β=110.45° γ=89.27° Z=2 4.83 black [3]
Sc7CI12 trigonal R3 a=14.717 c=9.847 Z=3 4.99 dark purple; dissolves in N,N-dimethylacetamide [4][5]
Sc24C10I30 trigonal PaШаблон:Overbar a=25.5182, c=25.5182 4.00 black; supertetrahedron of C10 [6]
Y2C2I2 monoclinic C12/m1 a=7174, b=3.866, c=10.412 β=92.98, 5.25 bronze; superconductor Tc=9.97K [2][7]
Y2I2C trigonal PШаблон:Overbarm1 a=3.922 c=10.404 5.32 olive green [2]
Y4I5C monoclinc C2/m a=18.479 b=3.947 c=8.472 β=103.22° 5.53 dark red; chains [8]
Y5C2I9 monoclinic C12/c1 a=18.479, b=3947, c=8472, β=103.22° 4.97 black [2]
Y6C2I7 monoclinc C2/m a=21.557 b=3.909 c=12.374 β=123.55° 5.53 black; twin chain [8][9]
Y10C2I13 monoclinc C2/m a=21.317 b=3.95 c=19.889 β=97.40° Z=2 black [9]
Y19C6I34 triclinic PШаблон:Overbar a=9.3683,b=10.341, c=22.173, α=79.104, β=88.175, γ=69.277 Z=1 1970.8 5.12 black [2]
Y10C2I13 monoclinic C12/m1 a=21.317, b=3.957, c19.899, β=97.4° 5.11 black [2]
Y19C6I34 triclinic PШаблон:Overbar a=93683, b=10.341, c=22.173, α=79.104°, β=88.175°, γ=69.277° 5.12 black [2]
Y16B4C8I19 triclinic PШаблон:Overbar a=12.311, b=13.996, c=19.695, α=74.96, β=89.51, γ=67.03 4.40 blue [10]
Y21B7C14I18 triclinic PШаблон:Overbar a=10.66, b=15.546, c=18.416, α=82.49, β=85.01, γ=82.92 Z=2 2995 4.87 [10][11]
Y6C2I9N hexagonal P6 a=20.275, c=13.025 4.91 brown [12]
Y7C2I12N triclinic PШаблон:Overbar a=9.7124, b=10.3038, c=16.7358, α=101.366, β=92.758, γ=112.799 4.84 olive green [12]
Y7C3I6O orthorhombic Pmma a=22.494, b=3.837, c=10.791 5.12 bronze [12]
[Y9C4O]I8 orthorhombic Pmmn a = 29.127, b = 3.8417, c = 10.80.29, Z = 2 5.16 black [13][14]
Y16C7I14O2 monoclinic C2/m a=51.6, b=3.84, c=10.8, β=93 5.15 [12]
YCI0.75l0.25C monoclinic C2/m a=7.127, b=3.839, c=10.441, β=93.84 4.78 [15]
YI0.75CBr0.25 monoclinic C2/m a=7.131, b=3.847, c=10.358, β=93.73 5.06 [16]
Zr6CI12 trigonal RШаблон:Overbar a=14.508, c=10.007 5.69 [2]
Zr6CI14 orthorhombic Cmce a=15.69, b=14.218, c=12.808 5.43 [2]
K0.58Zr6CI14 orthorhombic Cmca a=15.727, b=14.278, c=12798 5.54 [12]
RbZr6I14C orthorhombic Cmca a=15.768, b=14.296, c=12.849 5.55 [12]
CsY10C4I18 triclinic PШаблон:Overbar a=11.138, b=11.201, c=11.325, α=66.92, β=87.26, γ=60.87 Z=1 1117.2 4.99 black [17]
Cs2Zr7I18C trigonal RШаблон:Overbarc a=10.744, c=29.409 5.42 [18]
CsZr6I14C orthorhombic Cmca a=15.803, b=14.305, c=12.934 5.61 [18]
Cs2Zr7I18C trigonal RШаблон:Overbar a = 10.744, c = 29.409 Z=3 4.99 black [19]
LaIC monoclinic C12/m1 a=7.619, b=4.1252, c=10.7513, β=93.143 5.47 bronze [20]
LaIC monoclinic C12/m1 a=7.6132, b=4.1324, c=10.859, β=100.835 5.50 bronze [20]
La3I5C triclinic PШаблон:Overbar a=7.955, b=9.687, c=9.728, α=107.81, β=97.34, γ=105.56 5.28 violet [2]
La3C2I3 orthorhombic C2221 a=12.026 b=17.739 c=17.735 5.77 black [2]
La4C1.5I5 monoclinic C2/m a = 19.849, b = 4.1410, c = 8.956, β = 103.86° 5.62 metallic grey [21]
La4C2I5 orthorhombic Immm a = 19.907, b = 4.1482, c = 8.963, β = 104.36° [21]
La5C2I9 orthorhombic Pbca a = 8.025, b = 16.887, c = 35.886 Z=8 4863 5.08 >850° metallic green [22]
La5C2I9 triclinic PШаблон:Overbar a = 8.006, b = 10.088, c = 14.383, α = 79.34°, β = 80.75° and γ = 85.07° Z=2 1124.9 5.494 <800 °C; dark red; air sensitive [22][23]
La6I10(C2) triclinic PШаблон:Overbar a = 9.687, b = 9.728, c = 7.955, α = 97.34°, β = 105.56° and γ = 107.81° Z=1 699.33 5.276 violet; air sensitive [23]
La7C3I10 triclinic PШаблон:Overbar a=9.761, b=11.79, c=14.055, α=79.6, β=71.49, γ=65.79 5.42 greenish black [2]
La10C4I15 triclinic PШаблон:Overbar a=9.747, b=10.655, c=11.736, α=93.68, β=114.44, γ=109.28 5.45 dark red [20]
La10I15(C2)2 triclinic PШаблон:Overbar a = 9.747, b = 10.655, c = 11.736, α = 93.68°, β = 114.44° and γ = 109.28° Z=1 1018.39 5.447 dark red; air sensitive [23]
La12I17(C2)3 monoclinic C12/c1 a= 19.927, b= 12.636, c = 19.399, β = 90.24(1)°, Ζ = 4 4884.6 5.30 black [24]
La14(C2)3I20 triclinic PШаблон:Overbar a = 9.761, b = 11.790, c = 14.055, α = 79.60°, β = 71.49°, γ = 65.79° greenish black [25]
La4B2I5C monoclinic a=23.303, b=4.299, c=18.991, β=126.22 5.30 black [26]
La9B3C6I5 orthorhombic a=3.9481, b=33.857, c=8.218 6.01 [10]
La4I6CN tetragonal a=13.953 c=9.811 4.67 olive green [27]
LaCI0.75l0.25C monoclinic C2/m a=7.5764, b=4.0758, c=10.7266, β=93.384 5.12 bronze [15]
LaI0.75CBr0.25 monoclinic C2/m a=75857, b=4.0981, c=10.6782, β=93.272 5.33 bronze [16]
Ce3I5C triclinic PШаблон:Overbar a=7.875, b=9.588, c=9.648, α=107.69, β=97.24, γ=105.32 5.43 violet [28]
Ce5C2I9 orthorhombic Pbca a = 7.9284, b = 16.714, c = 35.530 5.27 red [22]
Ce6I10C2 triclinic PШаблон:Overbar a=9.588 b=9.648 c=7.875 α = 97.24°, β = 105.32° and γ = 107.69 Z=1 652.3 5.432 violet [23]
Ce7C3I10 triclinic PШаблон:Overbar a=9.688, b=11.67, c=13.932, α=80.16, β=71.81, γ=65.88 5.57 greenish black [28]
Ce12C6I17 monoclinic C12/c1 a=19.731, b=12.495, c=19.182, β=90.36 5.49 black; chains [28]
Ce14(C2)3I20 triclinic PШаблон:Overbar a = 9.688, b = 11.670, c = 13.932, α = 80.16°, β = 71.81°, γ = 65.88° greenish back; semiconductor [25]
Ce4B2I5C monoclinic a=23.194, b=4.29, c=18.822, β=126.5 5.42 black [26]
Ce8I6(C2)(N)2
Ce4I6CN tetragonal P42/mnm a = 13.877, c = 9.665 Z=4 1861.3 4.810 brown [29]
Ce6I9C2N hexagonal P6/m a = 41.774, c = 13.719 Z=32 20734 5.179 black; moisture sensitive [29]
Ce6I9C2N hexagonal P6/m a = 20.958, c = 13.793 Z=8 5246 5.117 black [29]
Pr{Pr6C}I12 black [30]
Pr7C3I10 triclinic PШаблон:Overbar a=9663, b=11.619, c=13.866, α=80.31, β=71.79, γ=65.9 5.64 black [2]
Pr12(C2)3I17 monoclinic C2/c a=19.610, b=12.406, c=19.062, β=90.45° 5.62 metallic grey [2][31]
Nd2C2I2 monoclinic C2/m layered [32]
Nd12(C2)3I17 monoclinic C2/c a=19.574, b=112.393, c=19.003(5) Å, β=90.41° 5.71 black [2][31]
Rb{Pr6C2}I12 triclinic PШаблон:Overbar a = 9.601, b = 9.570, c = 10.034, α = 71.74, β = 70.69, γ = 72.38°, Z = 1 805.6 5.11 black [33]
Cs2[Pr6(C2)]I12 triclinic PШаблон:Overbar a=9.481, b=9.536, c=10.052; α=71.01; β=84,68, γ=89.37°; Z=1 515.3 5.16 black [34]
Cs4[Pr6(C2)]I13 tetragonal I41/amd a = 18.049; c = 12.595 4.94 blue-black with brassy lustre [35]
Gd2IC hexagonal P63/mmc a=3.801, c=14.792 8.14 [36]
Gd3I3C monoclinic P121/m1 a=8.658, b=3.926, c=11.735, β=92.26 7.20 bronze; twin chains [36]
Gd4I5C monoclinic C2/m a=18.587 b=3.978 c=8.561 β=103.3 chains [37]
Gd6C2I7 monoclinic C2/m a=21.767 b=3.947 c=12.459 β=123.6 twin chains [37]
Gd7I12C trigonal RШаблон:Overbar a=15.288 c=10.291 [37]
Gd10C4I16 triclinic PШаблон:Overbar a=10.463 b=16.945 c=11.220 α=99.16 β=92.68 γ=88.06 6.18 black [38]
Gd12(C2)3I17 monoclinic C2/c a = 19.297, b = 12.201, c = 18.635, β = 90.37° 6.13 black; Gd6 octahedra containing C2 [39]
Gd4I6CN tetragonal a=13.578 c=9.313 5.48 brown red; air sensitive [27]
Gd4I6CN hexagonal a=40.806 c=9.232 5.65 brown red [27]
Gd19(C2)3I34 triclinic PШаблон:Overbar a = 9.4172, b = 10.339, c = 22.371, α = 79.00°, β = 88.32°, γ = 69.25° Z=1 2007.6 6.10 black; air sensitive [40]
[Gd4(C2)](Cl, I)6 tetragonal P4/mbm a = 13.475, c = 12.125, Z = 2 black [41]
Gd6C3I4.56Cl4.44 tetragonal P4/mbm a=13.475, c=12.125 5.18 black [15]
Tb2IC hexagonal P63/mmc a=3.7707, c=14.66 8.40 [2]
Tb2C2I2 monoclinic C2/m layered [42]
Dy2I3C orthorhombic Pnnm a=13.622, b=14.335, c=8.396 5.82 [43]
Dy5C2I9 monoclinic P121/c1 a=10.47, b=17.152, c=13.983, β=121.14 6.12 black [43]
Dy7C2I12 trigonal RШаблон:Overbar a=15.233, c=10.649 6.25 black [43]
Dy12(C2)3I17 monoclinic C2/c a=19.149, b=12.069, c=18.595, β=90.54 6.46 black [43][31]
{(C2)2O2Dy12}I18 hexagonal P6/m a = 20.2418, c = 12.9921, Z = 8 4610.1 6.22 black [44]
{(C2)2O2Dy14}I24 triclinic PШаблон:Overbar a = 9.730, b = 10.330, c = 16.770, α = 101.42°, β = 92.72°, γ = 112.75°, Z = 2 1509.3 5.94 black [44]
Ho7C2I12N triclinic PШаблон:Overbar a=9.688, b=10.287, c=16.678, α=101.31, β=92.78, γ=112.8 6.06 brown red [45]
[Ho9C4O]I8 orthorhombic Pmmn a=3.8157, b=28.867, c=10.748 7.19 [45][14]
Er4I5C monoclinic C2m a=18.521 b=4.015 c=8.478 β=103.07 [37]
Er6C2I7 monoclinic C2/m a=21.375 b=3.869 c=12.319 β=123.50 twin chains [37]
[Er9C4O]I8 orthorhombic Pmmn a=3.8037, b=28.818, c=10.7381 7.29 [46][14]
Cs[Er6C]I12 trigonal RШаблон:Overbar a=11.120 c=20.638 Z=3 443.71 6.02 black [47]
[Er14(C2)2(N)2]l24 triclinic PШаблон:Overbar a = 9.663, b = 10.276, c = 16.634, α =101.374°, β = 92.85°, γ = 112.83°, Z =2 1477.8 6.14 red brown [48]
CsEr10(C2)2I18 triclinic PШаблон:Overbar a=11.052 b=11.120 c=11.229 α=66.01° β=87.14° γ=60.80° Z=1 656.6 6.29 black [47]
[Lu9C4O]I8 orthorhombic Pmmn a=3.7575, b=28.333, c=10.6377 7.78 [12][14]

References

Шаблон:Reflist

Шаблон:Carbides Шаблон:Iodides

Партнерские ресурсы
Криптовалюты
Магазины
Хостинг
Разное

  1. ↑ Шаблон:Cite journal
  2. ↑ 2,00 2,01 2,02 2,03 2,04 2,05 2,06 2,07 2,08 2,09 2,10 2,11 2,12 2,13 2,14 2,15 Шаблон:Cite book
  3. ↑ 3,0 3,1 Шаблон:Cite journal
  4. ↑ Шаблон:Cite journal
  5. ↑ Шаблон:Cite journal
  6. ↑ Шаблон:Cite journal
  7. ↑ Шаблон:Cite journal
  8. ↑ 8,0 8,1 Шаблон:Cite journal
  9. ↑ 9,0 9,1 Шаблон:Cite journal
  10. ↑ 10,0 10,1 10,2 Шаблон:Cite book
  11. ↑ Шаблон:Cite journal
  12. ↑ 12,0 12,1 12,2 12,3 12,4 12,5 12,6 Шаблон:Cite book
  13. ↑ Шаблон:Cite journal
  14. ↑ 14,0 14,1 14,2 14,3 Шаблон:Cite journal
  15. ↑ 15,0 15,1 15,2 Шаблон:Cite book
  16. ↑ 16,0 16,1 Шаблон:Cite book
  17. ↑ Шаблон:Cite journal
  18. ↑ 18,0 18,1 Шаблон:Cite book
  19. ↑ Шаблон:Cite journal
  20. ↑ 20,0 20,1 20,2 Шаблон:Cite book
  21. ↑ 21,0 21,1 Шаблон:Cite journal
  22. ↑ 22,0 22,1 22,2 Шаблон:Cite journal
  23. ↑ 23,0 23,1 23,2 23,3 Шаблон:Cite journal
  24. ↑ Шаблон:Cite journal
  25. ↑ 25,0 25,1 Шаблон:Cite journal
  26. ↑ 26,0 26,1 Шаблон:Cite book
  27. ↑ 27,0 27,1 27,2 Шаблон:Cite journal
  28. ↑ 28,0 28,1 28,2 Шаблон:Cite book
  29. ↑ 29,0 29,1 29,2 Шаблон:Cite journal
  30. ↑ Шаблон:Cite journal
  31. ↑ 31,0 31,1 31,2 Шаблон:Cite journal
  32. ↑ Шаблон:Cite journal
  33. ↑ Шаблон:Cite journal
  34. ↑ Шаблон:Cite journal
  35. ↑ Шаблон:Cite journal
  36. ↑ 36,0 36,1 Шаблон:Cite book
  37. ↑ 37,0 37,1 37,2 37,3 37,4 Шаблон:Cite book
  38. ↑ Шаблон:Cite journal
  39. ↑ Шаблон:Cite journal
  40. ↑ Шаблон:Cite journal
  41. ↑ Шаблон:Cite journal
  42. ↑ Шаблон:Cite journal
  43. ↑ 43,0 43,1 43,2 43,3 Шаблон:Cite book
  44. ↑ 44,0 44,1 Шаблон:Cite journal
  45. ↑ 45,0 45,1 Шаблон:Cite book
  46. ↑ Шаблон:Cite book
  47. ↑ 47,0 47,1 Шаблон:Cite journal
  48. ↑ Шаблон:Cite journal
Источник — http://wikihandbk.com/ruwiki/index.php?title=Английская_Википедия:Carbide_iodide&oldid=13771040