Английская Википедия:Carbon nitride
Материал из Онлайн справочника
Перейти к навигацииПерейти к поиску
In organic chemistry, carbon nitrides are compounds consisting only of carbon and nitrogen atoms. Carbon nitrides are also known as organic semiconductors with a band gap of 2.7 eV. Due to its hydrogen-bonding motifs and electron-rich properties, this carbon material is considered a potential candidate for material applications in carbon supplementation.[1]
Covalent network compounds
- Beta carbon nitride - a solid with a formula β-Шаблон:Chem2, which is predicted to be harder than diamond.
- Graphitic carbon nitride - g-Шаблон:Chem2, with important catalytic and sensor properties.[2]
- Шаблон:Chem2 - a combined triazole and triazine framework.[3]
- MCN-12 (Шаблон:Chem2) and MCN-13 (Шаблон:Chem2).[4]
Azafullerenes
- Azafullerenes are a class of heterofullerenes in which the element substituting for carbon is nitrogen.[5] Examples include Шаблон:Chem2 (biazafullerenyl),[6] Шаблон:Chem2 (diaza[60]fullerene), Шаблон:Chem2 (triaza[60]fullerene) and Шаблон:Chem2.
Cyanofullerenes
- Cyanofullerenes are a class of modified fullerenes in which cyano- groups are attached to a fullerene skeleton. These have the formula Шаблон:Chem2, where n takes the values 1 to 9.
Cyanogen
- Cyanogen - Шаблон:Chem2 (Шаблон:Chem2)
- Isocyanogen - Шаблон:Chem2 (Шаблон:Chem2)
- Diisocyanogen - Шаблон:Chem2 (Шаблон:Chem2)
- Paracyanogen - a cyanogen polymer, Шаблон:Chem2
- Paraisocyanogen - a cyanogen polymer, Шаблон:Chem2
Percyanoalkynes, -alkenes and -alkanes
- dicyanoacetylene - Шаблон:Chem2 or Шаблон:Chem2, also called carbon subnitride or but-2-ynedinitrile
- tetracyanoethylene - Шаблон:Chem2 or Шаблон:Chem2
- tetracyanomethane - Шаблон:Chem2 or Шаблон:Chem2
- 2,2-diisocyanopropanedinitrile - Шаблон:Chem2 or Шаблон:Chem2
- hexacyanoethane - Шаблон:Chem2 or Шаблон:Chem2
- hexacyanocyclopropane - Шаблон:Chem2 or Шаблон:Chem2
- hexacyanobutadiene[7] - Шаблон:Chem2 or Шаблон:Chem2
Dicyanopolyynes
Dicyanopolyynes are composed of a chain of carbon atoms with alternating single and triple bonds, terminated by nitrogen atoms. Although not a polyyne dicyanoacetylene (Шаблон:Chem2) otherwise fits within this series.
- Шаблон:Chem2 or Шаблон:Chem2, Шаблон:Chem name (dicyanodiacetylene)
- Шаблон:Chem2 or Шаблон:Chem2, dicyanohexatriyne
- Шаблон:Chem2 or Шаблон:Chem2
- Шаблон:Chem2 or Шаблон:Chem2
- Шаблон:Chem2 or Шаблон:Chem2
- Шаблон:Chem2 or Шаблон:Chem2
- Шаблон:Chem2 or Шаблон:Chem2
- Шаблон:Chem2 or Шаблон:Chem2
- Шаблон:Chem2 or Шаблон:Chem2
Perazidoalkynes, -alkenes and -alkanes
Percyanoheterocycles
- pentacyanopyridine - Шаблон:Chem2
- tetracyanopyrazine - Шаблон:Chem2
- tricyanotriazine - Шаблон:Chem2[8]
- tetracyano-bitriazine - Шаблон:Chem2[8]
- dicyanotetrazine - Шаблон:Chem2
- hexacyanotrisimidazole - Шаблон:Chem2
- hexacyanohexaazatriphenylene - Шаблон:Chem2
Aromatic cyanocarbons
- hexacyanobenzene - Шаблон:Chem2
- octacyanonaphthalene - Шаблон:Chem2
- decacyanoanthracene - Шаблон:Chem2
Other compounds
- cyanonitrene - Шаблон:Chem2 or Шаблон:Chem2 (one of the nitrogens is univalent)
- azodicarbonitrile - Шаблон:Chem2 or Шаблон:Chem2, cis and trans isomers
- cyanogen azide - Шаблон:Chem2 or Шаблон:Chem2
- 1-diazidocarbamoyl-5-azidotetrazole - Шаблон:Chem2
- 2,2′-azobis(5-azidotetrazole) - Шаблон:Chem2
- triazidotriazine (cyanuric triazide) - Шаблон:Chem2 (Шаблон:Chem2)
- triazidoheptazine - Шаблон:Chem2 (Шаблон:Chem2)
- tricyanomethanimine (dicyanomethylene-cyanamide) - Шаблон:Chem2 or Шаблон:Chem2
- diazidodicyanoethylene - Шаблон:Chem2 or Шаблон:Chem2 and Шаблон:Chem2, cis and trans
- dicyanodiazomethane - Шаблон:Chem2 or Шаблон:Chem2
- Шаблон:Chem name - Шаблон:Chem2 or Шаблон:Chem2 (and isomers cyanoisocyanocarbene Шаблон:Chem2, diisocyanocarbene Шаблон:Chem2, 3-cyano-2H-azirenylidene and 3-isocyano-2H-azirenylidene)
- 1,3,5-triazido-2,4,6-tricyanobenzene - Шаблон:Chem2 (Шаблон:Chem2)
- nitrogen tricyanide Шаблон:Chem2 and carbon bis(cyanamide) Шаблон:Chem2, two formal monomers of polymeric Шаблон:Chem2
Anions and functional groups
- cyanide - Шаблон:Chem2 ion, cyanide Шаблон:Chem2 and isocyanide Шаблон:Chem2 functional groups
- dicyanamide - Шаблон:Chem2 or Шаблон:Chem2
- tricyanomethanide - Шаблон:Chem2 or Шаблон:Chem2
- pentacyanoethanide - Шаблон:Chem2 or Шаблон:Chem2
- pentacyanopropenide (pentacyanoallyl anion) - Шаблон:Chem2
- 2-dicyanomethylene-1,1,3,3-tetracyanopropanediide Шаблон:Chem2
- tricyanomelaminate anion - Шаблон:Chem2
- melonate - Шаблон:Chem2
- Шаблон:Chem name anions - Шаблон:Chem2 (n odd) and Шаблон:Chem2 (n even)
- cyanoacetlyide - Шаблон:Chem2 or Шаблон:Chem2
- cyanobutadiynylide - Шаблон:Chem2 or Шаблон:Chem2
- cyanopolyynide anions - Шаблон:Chem2 (n odd)
See also
References
Шаблон:Carbon compounds Шаблон:Authority control
- ↑ Шаблон:Cite book
- ↑ Шаблон:Cite journal
- ↑ I. Y. Kim, S. Kim, X. Jin, S. Premkumar, G. Chandra, N.-S. Lee, G. P. Mane, S.-J. Hwang, S. Umapathy, A. Vinu, Angew. Chem. Int. Ed. 2018, 57, 17135. Шаблон:Doi
- ↑ Kim, I. Y., Kim, S., Premkumar, S., Yang, J.-H., Umapathy, S., Vinu, A., "Thermodynamically Stable Mesoporous C3N7 and C3N6 with Ordered Structure and Their Excellent Performance for Oxygen Reduction Reaction". Small 2020, 16, 1903572. Шаблон:Doi
- ↑ D.J. Harris, Discovery of Nitroballs: Research in Fullerene Chemistry, 1993 California State Science Fair, http://www.usc.edu/CSSF/History/1993/S05.html Шаблон:Webarchive
- ↑ Hummelen et al, "Isolation of the Heterofullerene C59N as Its Dimer (C59N)2", Science 269: 1554-1556 (1995). Шаблон:Doi
- ↑ O.W.Webster, Hexacyanobutadiene, J. Am. Chem. Soc. 86(14): 2898–2902 (1964)
- ↑ 8,0 8,1 Sesto et al, "Chemical Reduction of 2,4,6-Tricyano-1,3,5-triazine and 1,3,5-Tricyanobenzene. Formation of Novel 4,4',6,6'-Tetracyano-2,2'-bitriazine and Its Radical Anion", J. Org. Chem. 68: 3367-3379 (2003). Шаблон:Doi
