Английская Википедия:Iron(III) azide

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Шаблон:Chembox

Iron(III) azide, also called ferric azide, is a chemical compound with the formula Шаблон:Chem2. It is an extremely explosive, impact-sensitive, hygroscopic dark brown solid. This compound is used to prepare various azidoalkanes,Шаблон:Clarify such as n-butyl azide.[1]

Preparation

This compound is prepared by the reaction of sodium azide and iron(III) sulfate in methanol:[1]

Шаблон:Chem2

Iron(III) azide can also be formed by pulse irradiationШаблон:Vague of a mixture of iron(II) perchlorate, sodium azide, and hydrogen peroxide.[2] Under these conditions, a neutral N3 radical is formed, which oxidizes the iron(II) to iron(III); the iron(III) then promptly combines with azide ions.

References

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Шаблон:Iron compounds Шаблон:Azides