Английская Википедия:1,2,3-Cyclohexatriene

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Версия от 02:32, 18 декабря 2023; EducationBot (обсуждение | вклад) (Новая страница: «{{Английская Википедия/Панель перехода}} {{Chembox <!-- Images --> | ImageFile = 1,2,3-cyclohexatriene v2.svg | ImageSize = 150px | ImageAlt = <!-- Names --> | IUPACName = Cyclohexa-1,2,3-triene | OtherNames = <!-- Sections --> | Section1 = {{Chembox Identifiers | CASNo = 90866-90-3 | ChEBI = 195206 | PubChem = 22138104 | StdInChI=1S/C6H6/c1-2-4-6-5-3-1/h1,6H,2,4H2 | StdInChI...»)
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Шаблон:Chembox

1,2,3-Cyclohexatriene is an unstable chemical compound with the molecular formula Шаблон:Chem2.[1] It is an unusual isomer of benzene in which the three double bonds are cumulated.

In 1990, 1,2,3-cyclohexatriene was first prepared by reacting a cyclohexadiene derivative with cesium fluoride.[2] The product was too reactive to be isolated on its own, so its existence was confirmed by trapping via a cycloaddition reaction.

Файл:1,2,3-cyclohexatriene reaction.svg
Preparation and trapping of 1,2,3-cyclohexatriene reaction
Шаблон:Clear-left

1,2,3-Cyclohexatriene and its derivatives undergo a variety of reactions including cycloadditions, nucleophilic additions, and σ-bond insertions,[3] and therefore they can be versatile reagents for organic synthesis.[4]

References

Шаблон:Reflist