Английская Википедия:4-Methylbenzyltrimethylammonium hydroxide

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Шаблон:Chembox

4-Methylbenzyltrimethylammonium hydroxide is a quaternary ammonium compound with the formula C11H18N+OH. It can be synthesized by reacting 4-methylbenzyl bromide with triethylamine, followed by stirring with silver oxide in water.[1]

Reactions

When heated with phenothiazine in toluene, it undergoes Hofmann elimination to form [2.2]Paracyclophane.[1]

Synthesis of 2.2-paracyclophane.

Paracycloheterophanes can be obtained by heating it with other quaternary ammonium hydroxides (e.g. with (5-methyl-2-thienylmethyl)trimethylammonium hydroxide to form [2.2]paracyclo(2,5)thiophenophane).[2]

References

Шаблон:Reflist

  1. 1,0 1,1 Шаблон:Cite journal
  2. Otsubo, T., Mizogami, S., Osaka, N., Sakata, Y., & Misumi, S. (1977). Layered Compounds. XLII. Syntheses and Properties of Layered Paracycloheterophanes. Bulletin of the Chemical Society of Japan, 50(7), 1841–1849. Шаблон:Doi