Английская Википедия:Aluminium dihydrogenphosphate

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Версия от 22:42, 29 января 2024; EducationBot (обсуждение | вклад) (Новая страница: «{{Английская Википедия/Панель перехода}} {{Chembox | ImageFile1 = Al(H2PO4)3simple.png | ImageSize1 = | ImageFile2 = Al(H2PO4)3CollCode15496.png | ImageSize2 = | ImageAlt = | IUPACName = | OtherNames = |Section1={{Chembox Identifiers | CASNo = 13530-50-2 | PubChem = 9818426 | EC_number = 236-875-2 | StdInChI=1S/Al.3H3O4P/c;3*1-5(2,3)4/h;3*(H3,1,2,3,4)/q+3;;;/p-3 | StdInChIKey = RGPUVZXXZFNFBF-UHFFFAOYSA-K | SMILES = OP(=...»)
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Шаблон:Chembox

Aluminium dihydrogenphosphate describes inorganic compounds with the formula Al(H2PO4)3.xH2O where x = 0 or 3. They are white solids. Upon heating these materials convert sequentially to a family of related polyphosphate salts including aluminium triphosphate (AlH2P3O10.2H2O), aluminium hexametaphosphate (Al2P6O18), and aluminium tetrametaphosphate (Al4(P4O12)3). Some of these materials are used for fireproofing and as ingredients in specialized glasses.[1]

According to analysis by X-ray crystallography, the structure consists of a coordination polymer featuring octahedral Al3+ centers bridged by tetrahedral dihydrogen phosphate ligands. The dihydrogen phosphate ligands are bound to Al3+ as monodentate ligands.[2]

References

Шаблон:Aluminium compounds