Английская Википедия:Benzotriyne

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Шаблон:Short description Шаблон:Chembox

Benzotriyne or cyclo[6]carbon is a hypothetical compound, an allotrope of carbon with molecular formula Шаблон:Chem2. The molecule is a ring of six carbon atoms, connected by alternating triple and single bonds.[1] It is, therefore, a potential member of the cyclo[n]carbon family.

There have been a few attempts to synthesize benzotriyne, e.g. by pyrolysis of mellitic anhydride,[2] but without success Шаблон:As of. Calculations suggest that the alternative cyclic cumulene structure, called cyclohexahexaene, is the potential energy minimum of the cyclo[6]carbon framework. It is unclear whether this second structure is an isomer or a limiting resonance structure.[3]

Файл:Benzotriyne explicit.png vs Файл:Cyclohexahexaene explicit.png

References

Шаблон:Reflist

Шаблон:Allotropes of carbon


Шаблон:Inorganic-compound-stub Шаблон:Organic-compound-stub Шаблон:Theoretical-chem-stub