Английская Википедия:Borane tert-butylamine
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Borane tert-butylamine is an amine borane complex derived from tert-butylamine and borane. It is a colorless solid.
The compound is prepared by the reaction of tert-butylammonium chloride and sodium borohydride:[1]
- t-BuNH3Cl + NaBH4 → t-BuNH2BH3 + H2 + NaCl
In organic synthesis, borane tert-butylamine can be used for selective reduction of certain functional groups including aldehydes, ketones, oximes, and imines.[2]
In photographic processing, it is used in the E-4 process, as "chemical enlighting" step in the processing of the film.
See also
References
- ↑ Girolami, G. S.; Rauchfuss, T. B. and Angelici, R. J., Synthesis and Technique in Inorganic Chemistry, University Science Books: Mill Valley, CA, 1999.Шаблон:ISBN
- ↑ Шаблон:Cite web