Английская Википедия:Borate bromide
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Шаблон:Short description The borate bromides are mixed anion compounds that contain borate and bromide anions. They are in the borate halide family of compounds which also includes borate fluorides, borate chlorides, and borate iodides.
List
name | chem | mw | crystal system | space group | unit cell Å | volume | density | comment | references |
---|---|---|---|---|---|---|---|---|---|
Li3B8O13Br | 395.21 | orthorhombic | Pca21 | a 17.3967(5)Å b 9.4077(3)Å c 6.6750 | 1092.45 | 2.403 | birefringence 0.088@1064 nm | [1] | |
Na3B4O7Br | hexagonal | P6522 | a = 8.146 c = 20.24 | 1163.1 | 2.605 | [2] | |||
Na11B21O36Br2 | 1215.72 | monoclinic | C2/c | a=15.722 b=8.951 c=24.087 β=100.728 Z=4 | 3330.3 | 2.425 | [3] | ||
KBOB | K3B6O10Br | 422.07 | trigonal | R3m | a=10.1153 c=8.8592 Z=3 | 785.02 | 2.678 | colourless | [4] |
K9[B4O5(OH)4]3(CO3)Br·7H2O | 1191.75 | hexagonal | P6_2c | a=11243 c=17.132 Z=2 | 1875 | 2.11 | band gap 5.65 eV | [5] | |
Zn2BO3Br·H2O | 287.48 | orthorhombic | P212121 | a=4.962 b=8.484 c=14.644 Z=4 | 616.5 | 3.097 | NLO 0.6x KDP | [6] | |
KZn2BO3Br2 | 345.92 | trigonal | R32 | a=4.9611 c=27.221 Z=3 | 580.2 | 2.970 | white | [7] | |
RbZn2BO3Br2 | 388.47 | trigonal | R32 | a=4.9618 c=28.199 Z=3 | 601.2 | 3.219 | white | [7] | |
Ag4B4O7Br2 | 746.52 | hexagonal | P6122 | a=8.8291 c=44.7416 Z=12 | 3020.5 | 4.92 | [8] | ||
Sn2B5O9Br | 515.34 | orthorhombic | Pnn2 | a = 11.398 b = 11.446 c = 6.553 Z=4 | 854.9 | 4.004 | birefringence=0.439 at 546 nm; SHG 4.8x; white | [9] | |
NaBa4(GaB4O9)2Br3 | 1326.00 | tetragonal | P42nm | a=12.33 c=6.91 Z=2 | 1053 | 4.18 | NLO 1.1x KDP | [10] | |
La[B5O8(OH)(H2O)2Br] | 448.87 | monoclinic | P21/n | a=6.520 b=15.213 c=10.704 β=90.017 Z=4 | 1061.6 | 2.808 | colourless | [11] | |
LaBOBr | La[B7O10(OH)3(H2O)Br] | 518.49 | monoclinic | P21/n | a=7.944 b=15.105 c=9.836 β=90 Z=4 | 1180.3 | 2.918 | [12] | |
Ce[B5O8(OH)(H2O)2Br] | 450.08 | monoclinic | P21/n | a=6.495 b=15.159 c=10.670 β=90.048 Z=4 | 1050.6 | 2.846 | colourless | [11] | |
CeBOBr | Ce[B6O9(OH)2(H2O)2Br]·0.5H2O | 500.89 | monoclinic | P21/n | a=8.1507 b=14.874 c=9.867 β=90.085 Z=4 | 1196.3 | 2.781 | [12] | |
PrBOBr | Pr[B6O9(OH)2(H2O)2Br]·0.5H2O | 501.68 | monoclinic | P21/n | a=8.1346 b=14.819 c=9.847 β=90.153 Z=4 | 1187.0 | 2.807 | green | [12] |
Pr[B5O8(OH)(H2O)2Br] | 450.87 | monoclinic | P21/n | a=6.4910 b=15.143 c=10.664 β=90.0440 Z=4 | 1048.2 | 2.857 | [11] | ||
NdBOBr | Nd2[B12O17.5(OH)5(H2O)4Br1.5]Br0.5·H2O | 1018.02 | orthorhombic | Fdd2 | a=30.6641 b=19.7946 c=16.0737 Z=16 | 9757.3 | 2.772 | purple | [12] |
Nd4[B18O25(OH)13Br3] | 1619.27 | monoclinic | P2/c | a=10.544 b=6.451 c=23.485 β=97.754 Z=2 | 1583 | 3.397 | purple | [11] | |
SmBOBr | Sm4[B18O25(OH)13Br3] | 1643.71 | monoclinic | P21/n | a=10.508 b=6.427 c=23.408 β=97.585 Z=2 | 1567 | 3.484 | [12] | |
Ba2BO3Br | P-3m1 | a = 5.516, c = 11.019, and Z = 2 | [13] | ||||||
Ba3BO3Br3 | triclinic | P-1 | a = 9.280, b = 9.349 c = 13.025, α = 92.71°, β = 98.29°, γ = 116.20° and Z = 4 | [13] | |||||
Ba7(BO3)3SiO4Br | orthorhombic | P63mc | [14] | ||||||
Ba7(BO3)3GeO4Br | 1354.31 | orthorhombic | Pbam | a=20.381 b=7.477 c=11.175 Z=4 | 1702.9 | 5.283 | [14] | ||
Pb2Ba3(BO3)3Br | 1082.74 | orthorhombic | C2221 | a=10.538 b=14.2878 c=8.107 Z=4 | 1220.7 | 5.891 | NLO 3.1×KDP; colourless | [15] |
References
Шаблон:Borates Шаблон:Bromides
- ↑ Шаблон:Cite journal
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- ↑ 7,0 7,1 Шаблон:Cite journal
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- ↑ 11,0 11,1 11,2 11,3 Шаблон:Cite journal
- ↑ 12,0 12,1 12,2 12,3 12,4 Шаблон:Cite journal
- ↑ 13,0 13,1 Шаблон:Cite journal
- ↑ 14,0 14,1 Шаблон:Cite journal
- ↑ Шаблон:Cite journal