Английская Википедия:Borophosphate

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The borophosphates are mixed anion compounds containing borate and phosphate anions, which may be joined together by a common oxygen atom. Compounds that contain water or hydroxy groups can also be included in the class of compounds.[1]

Borophosphates can be classified by whether or not they are hydrated, and the anion structure, which can be single, double, triple, isolated ring, isolated branched ring, simple chain, branched chain, loop chain, layers, or three-dimensional network.[1] The isolated anion compounds are the borate phosphates, which contain separate borate and phosphate groups. Some of the borophosphate structures resemble silicates.[1]

Related compounds include aluminophosphates, which have aluminium instead of boron, gallophosphates,[2] with gallium in place of boron, and by substituting the phosphate: boroarsenates, boroantimonates, and vanadoborates.

Formation

Borophosphates can be formed by heating compounds together at up to 900 °C. The products are dense, anhydrous, and do not contain organic substances.[2]

Solvothermal synthesis uses a non water solvent such as ethylene glycol to dissolve the product.[2]

The flux method crystallises from a molten flux of boric acid and sodium dihydrogen phosphate at around 171.[3]

The hydrothermal method heats the ingredients with water under pressure up to 200 °C. The ingredients are boric acid, phosphoric acid, metal salts, or organic bases. Products often contain hydrogen.[2]

The ionothermal synthesis method uses an ionic liquid such as 1-alkyl-3-methylimidazolium bromide as a solvent. This can be done at atmospheric pressure and temperatures under 100 °C.[2]

Characteristics

Borophosphate compounds have been investigated for magnetic, electrical, optical and catalytic properties. Some borophosphates are porous and so have surface for interaction on their interiors, not just their surface. They can reversibly absorb water, or have channels that can allow ions to conduct. The reflection of a labelled tetrahedron cannot be superimposed (even with rotation or movements), so the compounds containing phosphate and borate tetrahedrons can be non-centrosymmetric, or chiral.[2]

List

name formula crystal system space group unit cell Å volume density comment refs
Li[B3PO6(OH)3] looped chain B3O3 rings OH on B and P [1]
Li2B3PO8 PШаблон:Overbar [2]
Li3BP2O8 PШаблон:Overbar [2]
NH4BeBP2O8·Шаблон:SfracH2O cubic P213 zeolite-ANA structure [4]
(NH4)2[B3PO7(OH)2] looped chain B3O3 rings OH on B [1]
(NH4)2B2P3O11(OH) monoclinic P21/c a=15.774 b=7.5213 c=8.9661 β=106.93° Z=4 1020.0 2.238 [5]
(NH4)3H2[BOB(PO4)3] infinite chains [6]
(NH4)4[H2B2P4O16] tetragonal P41212 [2]
(NH4)2BP2O7(OH) tetragonal P41212 a=7.2162 c=14.8258 Z=4 772.03 2.046 [5]
Na2[BP2O7(OH)] orthorhombic Pna21 a=6.8236, b=20.7911, c=13.1446, Z=12 layers [7]
Na3B6PO13 orthorhombic Pnma a=9.3727, b=16.2307, c=6.7232, Z=4 8 member rings [3]
Na3BP2O8 monoclinic C2/c a=12.567, b=10.290, c=10.210, β=92.492, Z=2 infinite chains [3]
Na5[BOB(PO4)3)] infinite chains [6]
NaBeBP2O8·Шаблон:SfracH2O cubic P213 zeolite-ANA structure [4]
Na13(H2O)2[B6P11O42(OH)2]Cl2·H2O F23 [2]
MgBPO4(OH)2 P3121 [2]
dimagnesium (monohydrogen­monophosphate­dihydrogenmonoborate­monophosphate) Mg2[BP2O7(OH)3] triclinic P1 a=6.452, b=6.455, c=8.360, α=82.50, β=82.56, γ=80.98, Z=1 338.8 triple [8]
(H3O)Mg(H2O)2[BP2O8]·H2O P6122 [2]
Mg3(H2O)6(B(OH)3PO4)2 double [1]
LiMg(H2O)2[BP2O8]·H2O P6522 [2]
NaMg(H2O)2[BP2O8]•H2O hexagonal P6122 a=9.428, c=15.820 loop branched chain [9]
Na2[MgB3P2O11(OH)]·Шаблон:SfracH2O hexagonal P63 a=11.771, c=12.100, Z=6 2.537 colourless [10]
K2B2P2O9 orthorhombic P212121 a=7.8227 b=8.1393 c=12.925 Z=4 822.9 2.468 [5]
K2BP2O7(OH) orthorhombic P212121 a=7.068 b=7.2396 c=14.116 Z=4 722.3 2.574 [5]
K3B4PO10 triclinic PШаблон:Overbar a=6.546, b=6.567, c=12.930, α=86.04, β=81.40, γ=60.42, Z=2 477.9 2.443 colourless 2D sheet [11]
K7B2P5O19 [2]
K3[B5PO10(OH)3] loop branch [1]
LiK2BP2O8 P21/n [2]
Li3K2BP4O14 Cmca [2]
KBeBP2O8·Шаблон:SfracH2O cubic P213 a=12.427, Z=12 1,919 zeolite-ANA structure [4]
KMg(H2O)2[BP2O8]•H2O hexagonal P6122 a=9.463, c=15.815 loop branched chain [9]
Ca[BPO5] loop branch B2PO3 rings [1]
Sc(H2O)2[BP2O8]·H2O hexagonal P6522 a=9.5752, c=15.8145, Z=6 1,255.7 2.378 [12]
Sc(H2O)2[BP2O8] hexagonal P6522 a=9.535, c=15.768, Z=6 [12]
NaSc[BP2O6(OH)3]·HPO4 P21/c [2]
Ti[BP2O7(OH)3] I41/amd [2]
V2[B(PO4)3] [13]
(VO)2BP2O10 [14]
Li3V2[BP3O12(OH)][HPO4] P21/c [2]
Na2[VB3P2O12(OH)]·2.92H2O I-43m [13]
NH4VIII[BP2O8(OH)] monoclinic P21/c a=9.425, b=8.269, c=9.697, β=102.26°, Z=4 738.5 [15]
Шаблон:Bracket3.8(H3O)1.2[(VIVO)4(BO)2(PO4)5]·0.3H2O monoclinic C2/c a=9.4737, b=22.144, c=17.219, β=105.936°, Z=4 layered [16]
Шаблон:Bracket2[Na(VO)10B(O)2(OPO3H)2}5]·22.5H2O [17]
Шаблон:Bracket4H[NH4(VO)12{B(O)2(OPO3)2}6]·14H2O orthorhombic Pbca a=21.45, b=16.315, c=29.65, Z=4 10378 1.920 [18]
Шаблон:Bracket4H[K(VO)12{O3POB(O)2OPO3}6]·16H2O orthorhombic Pbca a=21.537, b=16.267, c=29.717, Z=4 10411 1.996 [18]
KV[BP2O8(OH)] triclinic PШаблон:Overbar [2]
Cr2[B(PO4)3] P63/m [13]
Na{Cr[BP2O7(OH)3]} monoclinic C2/c a=10.4220, b=8.2468, c=9.2053, β=116.568°, Z=4 707.63 [19]
Na8[Cr4B12P8O44(OH)4][P2O7]·nH2O I23 [2]
Na11K5[NaCr8B4P12O60H8]·H2O Pmnn [2]
H2Mn5(H2O)6[BP2O8]4•4H2O hexagonal P6122 a=9.655, c=15.791, Z=1.5 pale pink [20]
Mn[BPO4(OH)2] P3221 a=7.5750, c=12.927, Z=6 642.37 3.020 [21]
LiMn(H2O)2[BP2O8(OH)]·H2O P6522 [2]
[NH4]4[Mn9B2(OH)2(HPO4)4(PO4)6] monoclinic C2/c a=32.603, b=10.617, c=10.718, β=108.26°, Z=4 3523 2.971 light pink [22]
(NH4)6[Mn3B6P9O36(OH)3]·4H2O C2 [2]
(NH4)7Mn4(H2O)[B2P4O15(OH)2]2[H2PO4][HPO4] Pnma [2]
(C3H12N2)[MnB2P3O12(OH)] [2]
(C4H12N2)[MnB2P3O12(OH)] Ima2 [2]
NaMn(H2O)2[BP2O8]•H2O hexagonal P6122 a=9.589, c=15.939 loop branched chain [9]
Na5(H3O){Mn3[B3O3(OH)]3(PO4)6}·2H2O hexagonal P63/m a=11.9683, c=12.1303, Z=2 [23]
Na5(NH4)Mn3[B9P2O33(OH)3]·Шаблон:SfracH2O P63 [2]
Na2[MnB3P2O11(OH)]·Шаблон:SfracH2O hexagonal P63 a=11.940, c=12.098, Z=6 2.670 colourless [10]
KMnBP2O7(OH)2 monoclinic P21/c a=6.659, b=12.049, c=9.790, β=109.12°, Z=4 742.2 orange-red luminescence [24]
KMn(H2O)2[BP2O8]•H2O hexagonal P6122 a=9.639, c=15.931 loop branched chain [9]
K5Mn2B2P5O19(OH)2 P21/n [2]
FeIII2[B(PO4)3] P63/m [13]
Fe[B2P2O7(OH)5] monoclinic C2/c a=17.745, b=6.720, c=7.059, β=109.01°, Z=4 796 2.808 unbranched chain [1]
Fe(H2O)2BP2O8·H2O hexagonal a=9.4583, c=15.707, Z=6 1216.9 2.543 [25]
Fe[BPO4(OH)2] P3221 a=7.4844, c=12.844, Z=6 623.06 3.129 [21]
FeII(H2O)2[B2P2O8(OH)2]·H2O P21/c [2]
Fe1.834IIFe0.166IIIB0.5[PO3(OH)]0.8(HPO3)2.033 cubic IШаблон:Overbar3d a=21.261, Z=48 [26]
NH4FeIII[BP2O8(OH)] monoclinic P21/c a=9.393, b=8.285, c=9.689, β=102.07°, Z=4 737.4 [15]
(NH4)0.75Fe(H2O)2[BP2O8]·Шаблон:SfracH2O P6522 [2]
(C3H12N2)[FeB2P3O12(OH)] Ima2 [2]
(C4H12N2)[FeB2P3O12(OH)] Ima2 [2]
(dienH3)(dienH2)0.5[FeII*III2B4P7O26(OH)4] PШаблон:Overbar [2]
NaFe[BP2O7(OH)3] triple
sodium diaquoiron(II) catena-[monoboro-diphosphate] monohydrate NaFe(H2O)2[BP2O8]•H2O hexagonal P6122 a=9.499, c=15.931 loop branched chain [9]
Na2[FeB3P2O11(OH)]·Шаблон:SfracH2O hexagonal P63 a=11.812, c=12.067, Z=6 2.742 light yellow [10]
potassium diaquoiron(II) catena-[monoboro-diphosphate] hemihydrate KFe(H2O)2[BP2O8]•H2O hexagonal P6122 a=9.510, c=15.952 loop branched chain [9]
K2Fe2[B2P4O16(OH)2] monoclinic P21/c a=9.372, b=8.146, c=9.587, β=101.18°, Z=2 718.0 B2P2O4 ring with phosphate sides [27]
KFeBP2O8(OH) P21/c [2]
CaFe[BP2O7(OH)3] C2/c [2]
Ca0.5Fe(H2O)2[BP2O8]·H2O P6522 [2]
Co5[BP3O14] double + phosphate [1]
Co3[BPO7] monoclinic Cm a=9.774, b=12.688, c=4.9057, β=119.749°, Z=4 528.2 [28]
Co[BPO4(OH)2] P3121 a=7.4554, c=12.7397, Z=6 613.24 3.229 [21]
(NH4)7Co4(H2O)[B2P4O15(OH)2]2[H2PO4][HPO4] Pnma [2]
(NH4)8[Co2B4P8O30(OH)4] P1 [2]
CoII(H2O)2[B2P2O8(OH)2]·H2O P21/c [2]
[Co(en)3][B2P3O11(OH)2] [29]
CoB2P3O12(OH)·H2en [30]
Co(C4H12N2)[B2P3O12(OH)] orthorhombic Ima2 a=12.4635, b=9.4021, c=11.4513, Z=4 1341.90 [31]
H2Co5(H2O)6[BP2O8]4•4H2O hexagonal P6122 a=9.639, c=15.931, Z=1.5 purple
LiCo(H2O)2[BP2O8]·H2O P6522
NaCo(H2O)2[BP2O8]•H2O hexagonal P6122 a=9.455, c=15.847 loop branched chain [9]
NaCoH2BP2O9 monoclinic P21/c a=6.547, b=11.404, c=9.650, β=107.37 687.6 2.905 pink; discovered in Tunisia [32]
Na2[CoB3P2O11(OH)]·Шаблон:SfracH2O hexagonal P63 a=11.759, c=12.099, Z=6 2.781 purple [10]
Na5(H3O){Co3[B3O3(OH)]3(PO4)6}·2H2O hexagonal P63/m a=11.7691, c=12.112, Z=2 [23]
Na6Co3B2P5O21Cl·H2O Pnma
KCo(H2O)2[BP2O8]•H2O hexagonal P6122 a=9.483, c=15.827 loop branched chain [9]
CaCo(H2O)[BP2O8(OH)]·H2O PШаблон:Overbar [2]
(K0.17Ca0.42)Co(H2O)2[BP2O8]·H2O P6522 [2]
(Co0.6Mn0.4)2(H2O)[BP3O9(OH)4] P212121 [2]
cobalt borophosphate ethylenediamine CoB2P3O12(OH)·en orthorhombic Pbca a=9.3501, b=12.2426, c=20.880 2,390.1 2.471 purple; layered [33][34]
(NH4)7Co4(H2O)[B2P4O15(OH)2]2[H2PO4][HPO4] Orthorhombic Pnma a=16.9206, b=10.5592, c=22.000, Z=4 3,930.6 2.386 pink [35]
(NH4)2(C4H12N2)[Co2B4P6O24(OH)2]·H2O I41/a [2]
NiBPO4(OH)2 P3121 [2]
Ni(H2O)2[B2P2O8(OH)2]·H2O P21/c [2]
LiNi(H2O)2[BP2O8]·H2O P6522 [2]
NaNi(H2O)2[BP2O8]•H2O hexagonal P6122 a=9.371, c=15.831 loop branched chain [9]
Na2[NiB3P2O11(OH)]·Шаблон:SfracH2O hexagonal P63 a=11.728, c=12.074, Z=6 2.799 yellow [10]
Na5(H3O){Ni3[B3O3(OH)]3(PO4)6}·2H2O hexagonal P63/m a=11.7171, c=12.0759, Z=2 [23]
KNi(H2O)2[BP2O8]•H2O hexagonal P6122 a=9.392, c=15.842 loop branched chain [9]
Cu3[B2P3O12(OH)3] monoclinic Cc a=6.1895, b=13.6209, c=11.9373, β=97.62°, Z=4 997.5 [36]
Cu(H2O)2[B2P2O8(OH)2] [37]
Cu2(H2O)[BP2O8(OH)] Pbca [2]
LiCu2[BP2O8(OH)2] C2/c [2]
LiCu2[BP2O8(OH)2] P212121 [2]
Na2[CuB3P2O11(OH)]·Шаблон:SfracH2O hexagonal P63 a=11.554, c=12.314, Z=6 2.862 sky-blue [10]
Na4Cu3[B2P4O15(OH)2]•2HPO4 ring with side phosphate and extra phosphate
Na5KCu3[B9P6O33(OH)3]·H2O P63/m [2]
Zn(C4H12N2)[B2P3O12(OH)] orthorhombic Ima2 a=12.4110, b=9.4550, c=11.4592, Z=4 1344.69 [31]
lithium zinc diaqua catena-[monoboro-diphosphate]-monohydrate LiZn(H2O)2[BP2O8] · H2O hexagonal P61 a=9.469, c=15.667, Z=6 1216.6 spiral ribbons [38]
Na[ZnBP2O8]⋅H2O hexagonal P6122 a=9.5404, c=14.7780, Z=6 1164.88 [39]
NaZn(H2O)2[BP2O8]•H2O hexagonal P6122 a=9.456, c=15.828 loop branched chain [9]
Na2[ZnB3P2O11(OH)]·Шаблон:SfracH2O hexagonal P63 a=11.963, c=12.363, Z=6 2.683 colourless [10]
NH4[ZnBP2O8] triclinic PШаблон:Overbar a=7.437, b=7.612, c=7.850, α=119.05, β=101.59, γ=103.43, Z=2 351.18 2.687 [40]
Na[ZnBP2O8] triclinic PШаблон:Overbar [2]
K[ZnBP2O8] monoclinic C2/c a=12.617, b=12.773, c=8.415, β=91.25°, Z=8 1355.8 2.991 [40]
Шаблон:Bracket1.5[Zn6B6P12O48]·Шаблон:SfracH2O hexagonal P6522 a=9.6685, c=14.8879; Z=1 [41]
RBPO Rb3B11P2O23 Triclinic P1 a=7.785, b=7.839, c=7.963, α=89,774, β=89.129, γ=88.211, Z=2 485.6 2.753 transparent above 168 nm; SHG 2.5× KDP; birefringence =0.071@1064 nm [42]
Rb[P2B2O8(OH)] network [1]
Li3Rb2BP4O14 Cmca [2]
K2RbB4PO10 triclinic PШаблон:Overbar a=6.5577, b=6.5931, c=13.098, α=84.626, β=80.514, γ=60.457, Z=2 485.9 2.719 colourless [11]
K2RbB8PO16 birefringence 0.057@1064 nm [43]
Rb2Co3(H2O)2[B4P6O24(OH)2] orthorhombic Pbca a = 9.501, b = 12.272, c = 20.074, Z = 4 [44]
Rb[ZnBP2O8] triclinic PШаблон:Overbar a=7.439, b=7.639, c=7.861, α=118.82, β=101.73, γ=103.51, Z=2 353.4 3.304 [40]
Sr[BPO5] P3221 loop branch B2PO3 rings [1]
KSrBP2O8 IШаблон:Overbar2d a=7.109, c=13.882 [45]
SrFe[BP2O8(OH)2] C2/c [2]
SrCo2BPO7 monoclinic P21/c a=6.485, b=9.270, c=10.066, β=111.14, Z=4 548.7 red [46]
AgMg(H2O)2[BP2O8]·H2O P6522 [2]
Шаблон:SfracH2O P6522 [2]
(Ag0.57Ni0.22)Ni(H2O)2[BP2O8]·Шаблон:SfracH2O P6522 [2]
Na3Cd3BP4O16 orthorhombic Pmc21 a=13.6854, b=5.335, c=18.2169, Z=4 SHG 1.1×KDP [2][47]
NH4Cd(H2O)2(BP2O8)·0.72H2O hexagonal P65 a=9.698, c=16.026, Z=6 1305.3 2.886 colourless [48]
In2[B(PO4)3] P63/m [13]
Cs[P2B2O8(OH)] 3D network [1]
Li2Cs2B2P4O15
K2CsB4PO10 triclinic PШаблон:Overbar a=6.6235, b=6.6243, c=13.273, α=79.734, β=86.558, γ=60.095, Z=2 496.46 2.979 colourless [11]
Cs2Cr3(BP4O14)(P4O13) monoclinic P21/c a=14.7918, b=15.819, c=9.7037, β=92.450, Z=4 876.9 3.257 green; [B(P2O7)2]5− [49]
CsFe(BP3O11) orthorhombic Pnma a=8.5375, b=12.7829, c=8.3346, Z=4 909.59 3.434 [N(PO4)(P2O7)]4- [49]
Cs2Co3(H2O)2[B4P6O24(OH)2] orthorhombic Pbca a=9.5526, b=12.3190, c=20.1123 2366.8 pink [2][50]
Cs[ZnBP2O8] triclinic PШаблон:Overbar a=7.506, b=7.914, c=8.038, α=1198.05, β=102.96, γ=104.50, Z=2 373.9 3.545 [40]
Ba[BPO5] P3221 [2]
Ba[BP3O12] orthorhombic Ibca a=7.066, b=14.268, c=22.159 2233.9 4.209 [1][51]
KBaBP2O8 IШаблон:Overbar2d a=7.202, c=14.300 [45]
BaFe[BP2O8(OH)] PШаблон:Overbar [2]
BaCo[BP2O8(OH)] PШаблон:Overbar [2]
Pb[BPO5] loop branch B2PO3 rings [1]
Pb3[(PO4)2BPO4] orthorhombic Pbca a=6.946, b=14.199, c=21.116, Z=8 2082.5 5.851 open branch, 2 PO4 extra on each B [51]
Na3PbII[B(O3POH)4] I41/a [2]
KPbBP2O8 IШаблон:Overbar2d [2]
PbII4Cl{Co2[B(OH)2P2O8](PO4)2]} RШаблон:Overbarc [2]
RbPbBP2O8 IШаблон:Overbar2d [2]
BiCo2BP2O10 P21/m [2]
BiNi2BP2O10 P21/m [2]
K2(UO2)12[B(H2PO4)4](PO4)8(OH)(H2O)6 tetragonal IШаблон:Overbar2m a=21.8747, c=7.0652 3380.7 [52]
K5(UO2)2[B2P3O12(OH)]2(OH)(H2O)2 monoclinic P21 a=6.7623, b=19.5584, c=11.0110, β=95.579° 1449.42 [52]
Ag2(NH4)3{(UO2)2[B3O(PO4)4(HPO4)2]}·H2O PШаблон:Overbar [2]
Ag2−x(NH4)3{(UO2)2[B2P5−yAsyO20−x(OH)x]} Pcmn [2]
Cs3(UO2)3[B(PO4)4]∙(H2O)0.5 P41212 a=12.2376, c=33.9468, Z=4 5083.8 yellow; microporous [53]

References

Шаблон:Reflist

Шаблон:Borates

Партнерские ресурсы
Криптовалюты
Магазины
Хостинг
Разное

  1. ↑ 1,00 1,01 1,02 1,03 1,04 1,05 1,06 1,07 1,08 1,09 1,10 1,11 1,12 1,13 1,14 Шаблон:Cite journal
  2. ↑ 2,00 2,01 2,02 2,03 2,04 2,05 2,06 2,07 2,08 2,09 2,10 2,11 2,12 2,13 2,14 2,15 2,16 2,17 2,18 2,19 2,20 2,21 2,22 2,23 2,24 2,25 2,26 2,27 2,28 2,29 2,30 2,31 2,32 2,33 2,34 2,35 2,36 2,37 2,38 2,39 2,40 2,41 2,42 2,43 2,44 2,45 2,46 2,47 2,48 2,49 2,50 2,51 2,52 2,53 2,54 2,55 2,56 2,57 2,58 2,59 2,60 2,61 2,62 2,63 2,64 2,65 2,66 2,67 2,68 2,69 Шаблон:Cite journal
  3. ↑ 3,0 3,1 3,2 Шаблон:Cite journal
  4. ↑ 4,0 4,1 4,2 Шаблон:Cite journal
  5. ↑ 5,0 5,1 5,2 5,3 Шаблон:Cite journal
  6. ↑ 6,0 6,1 Шаблон:Cite journal
  7. ↑ Шаблон:Cite journal
  8. ↑ Шаблон:Cite journal
  9. ↑ 9,00 9,01 9,02 9,03 9,04 9,05 9,06 9,07 9,08 9,09 9,10 Шаблон:Cite journal
  10. ↑ 10,0 10,1 10,2 10,3 10,4 10,5 10,6 Шаблон:Cite journal
  11. ↑ 11,0 11,1 11,2 Шаблон:Cite journal
  12. ↑ 12,0 12,1 Шаблон:Cite journal
  13. ↑ 13,0 13,1 13,2 13,3 13,4 Шаблон:Cite journal
  14. ↑ Шаблон:Cite journal
  15. ↑ 15,0 15,1 Шаблон:Cite journal
  16. ↑ Шаблон:Cite journal
  17. ↑ Шаблон:Cite journal
  18. ↑ 18,0 18,1 Шаблон:Cite journal
  19. ↑ Шаблон:Cite journal
  20. ↑ Шаблон:Cite journal
  21. ↑ 21,0 21,1 21,2 Шаблон:Cite journal
  22. ↑ Шаблон:Cite journal
  23. ↑ 23,0 23,1 23,2 Шаблон:Cite journal
  24. ↑ Шаблон:Cite journal
  25. ↑ Шаблон:Cite journal
  26. ↑ Шаблон:Cite journal
  27. ↑ Шаблон:Cite journal
  28. ↑ Шаблон:Cite journal
  29. ↑ Шаблон:Cite journal
  30. ↑ Шаблон:Cite journal
  31. ↑ 31,0 31,1 Шаблон:Cite journal
  32. ↑ Шаблон:Cite journal
  33. ↑ Шаблон:Cite journal
  34. ↑ Шаблон:Cite journal
  35. ↑ Шаблон:Cite journal
  36. ↑ Шаблон:Cite journal
  37. ↑ Шаблон:Cite journal
  38. ↑ Шаблон:Cite journal
  39. ↑ Шаблон:Cite journal
  40. ↑ 40,0 40,1 40,2 40,3 Шаблон:Cite journal
  41. ↑ Шаблон:Cite journal
  42. ↑ Шаблон:Cite journal
  43. ↑ Шаблон:Cite journal
  44. ↑ Шаблон:Cite journal
  45. ↑ 45,0 45,1 Шаблон:Cite journal
  46. ↑ Шаблон:Cite journal
  47. ↑ Шаблон:Cite journal
  48. ↑ Шаблон:Cite journal
  49. ↑ 49,0 49,1 Шаблон:Cite journal
  50. ↑ Шаблон:Cite journal
  51. ↑ 51,0 51,1 Шаблон:Cite journal
  52. ↑ 52,0 52,1 Шаблон:Cite journal
  53. ↑ Шаблон:Cite web
Источник — http://wikihandbk.com/ruwiki/index.php?title=Английская_Википедия:Borophosphate&oldid=13595792