Английская Википедия:Carbon chauvinism

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Файл:Glassy carbon and a 1cm3 graphite cube HP68-79.jpg

A large sample of glassy carbon, and a nearby 1 cm³ graphite cube

Carbon chauvinism is a neologism meant to disparage the assumption that the chemical processes of hypothetical extraterrestrial life must be constructed primarily from carbon (organic compounds) because as far as is known, carbon's chemical and thermodynamic properties render it far superior to all other elements at forming molecules used in living organisms.

The expression "carbon chauvinism" is also used to criticize the idea that artificial intelligence can't in theory be sentient or truly intelligent because the underlying matter isn't biological.

Concept

The term was used as early as 1973, when scientist Carl Sagan described it and other human chauvinisms that limit imagination of possible extraterrestrial life. It suggests that human beings, as carbon-based life forms who have never encountered any life that has evolved outside the Earth's environment, may find it difficult to envision radically different biochemistries.

Carbon alternatives

Файл:Silicon-unit-cell-3D-balls.png

Silicon in a diamond cubic crystal structure

Like carbon, silicon can form four stable bonds with itself and other elements, and long chemical chains known as silane polymers, which are very similar to the hydrocarbons essential to life on Earth. Silicon is more reactive than carbon, which could make it optimal for extremely cold environments. However, silanes spontaneously burn in the presence of oxygen at relatively low temperatures, so an oxygen atmosphere may be deadly to silicon-based life. On the other hand, it is worth considering that alkanes are as a rule quite flammable, but carbon-based life on Earth does not store energy directly as alkanes, but as sugars, lipids, alcohols, and other hydrocarbon compounds with very different properties. Water as a solvent would also react with silanes, but again, this only matters if for some reason silanes are used or mass-produced by such organisms.

Silicon lacks an important property of carbon: single, double, and triple carbon-carbon bonds are all relatively stable. Aromatic carbon structures underpin DNA, which could not exist without this property of carbon. By comparison, compounds containing silene double bonds (such as silabenzene, an unstable analogue of benzene) exhibit far lower stability than the equivalent carbon compound. A pair of silane single bonds have significantly greater total enthalpy than a single silene double bond, so simple disilenes readily autopolymerise, and silicon favors the formation of linear chains of single bonds (see the double bond rule).

Hydrocarbons and organic compounds are abundant in meteorites, comets, and interstellar clouds, while their silicon analogs have never been observed in nature. Silicon does, however, form complex one-, two- and three-dimensional polymers in which oxygen atoms form bridges between silicon atoms. These are termed silicates. They are both stable and abundant under terrestrial conditions, and have been proposed as a basis for a pre-organic form of evolution on Earth (see clay hypothesis).

The black cloud

Fred Hoyle (1915-2001), a prominent astronomer at the Institute of Astronomy at Cambridge, is most well known for his theory of how chemical elements heavier than helium in our universe are manufactured within stars. However, he is also remembered for his scientifically plausible fiction novels, the first of which “The Black Cloud” was published in 1957. This novel describes the interaction of Earth scientists with an intelligent life form, an immense black cloud of gas that moves directly towards the solar system and temporarily obscures the sun. When the black cloud detects radio signals from earth, it is surprised to discover that intelligent life can also exist on the surface of planets. Although Fred Hoyle characterizes this novel as a “frolic,” he also notes that there is little in the novel that could not conceivably happen. This novel is notable for raising, and providing a scientific rationale for the concept that the existence of “life” may not be constrained by the conditions that are ordinarily considered to be essential based on the singular example of life on earth.