Английская Википедия:Carbon tetroxide

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Версия от 01:20, 15 февраля 2024; EducationBot (обсуждение | вклад) (Новая страница: «{{Английская Википедия/Панель перехода}} {{Redirect|CO4|the Colchester postal district|CO postcode area}} {{Chembox | ImageFileL1 = Carbon tetroxide.svg | ImageFileR1 = Chemfm carbon tetroxyde.svg | IUPACName = C<sub>2v</sub> isomer: * 1,2,3-Trioxetan-4-one * Oxygen carbonate * Monooxygen carbonate D<sub>2d</sub> isomer: * Carbon diperoxide | OtherNames = C<sub>2v</sub> isomer: * 4-Trioxetanone * Trioxetan-4-one D<sub>2d</sub...»)
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Carbon tetroxide or Oxygen carbonate (in its C2v isomer) is a highly unstable oxide of carbon with formula Шаблон:Chem. It was proposed as an intermediate in the O-atom exchange between carbon dioxide (Шаблон:Chem) and oxygen (Шаблон:Chem) at high temperatures.[1] The C2v isomer, which is 138 kJ mol−1 more stable than the D2d isomer, was first detected in electron-irradiated ices of carbon dioxide via infrared spectroscopy.[2]

Файл:Carbon tetroxide D2d.svg
The D2d isomer of carbon tetroxide

The isovalent carbon tetrasulfide CS4 is also known from inert gas matrix. It has D2d symmetry with the same atomic arrangement as CO4 (D2d).[3]

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References

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Шаблон:Oxides of carbon Шаблон:Inorganic compounds of carbon


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