Английская Википедия:Cobalt(II) carbonate

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Шаблон:Chembox Cobalt(II) carbonate is the inorganic compound with the formula CoCO3. This reddish paramagnetic solid is an intermediate in the hydrometallurgical purification of cobalt from its ores. It is an inorganic pigment, and a precursor to catalysts.[1] Cobalt(II) carbonate also occurs as the rare red/pink mineral spherocobaltite.[2]

Preparation and structure

It is prepared by combining solutions cobaltous sulfate and sodium bicarbonate:

CoSO4 + 2 NaHCO3 → CoCO3 + Na2SO4 + H2O + CO2

This reaction is used in the precipitation of cobalt from an extract of its roasted ores.[1]

CoCO3 adopts a structure like calcite, consisting of cobalt in an octahedral coordination geometry.[3]

Reactions

Like most transition metal carbonates, cobalt carbonate is insoluble in water, but is readily attacked by mineral acids:

CoCO3 + 2 HCl + 5 H2O → [Co(H2O)6]Cl2 + CO2

It is used to prepare many coordination complexes. The reaction of cobalt(II) carbonate and acetylacetone in the presence of hydrogen peroxide gives tris(acetylacetonato)cobalt(III).[4]

Heating the carbonate proceeds in a typical way for calcining, except that the product becomes partially oxidized:

6Шаблон:NbspCoCO3 + O2 → 2Шаблон:NbspCo3O4 + 6Шаблон:NbspCO2

The resulting Co3O4 converts reversibly to CoO at high temperatures.[5]

Uses

Cobalt carbonate is a precursor to cobalt carbonyl and various cobalt salts. It is a component of dietary supplements since cobalt is an essential element. It is a precursor to blue pottery glazes, famously in the case of Delftware.

Related compounds

At least two cobalt(II) carbonate-hydroxides are known: Co2(CO3)(OH)2 and Co6(CO3)2(OH)8·H2O.[6]

The moderately rare spherocobaltite is a natural form of cobalt carbonate, with good specimens coming especially from the Republic of Congo. "Cobaltocalcite" is a cobaltiferous calcite variety that is quite similar in habit to spherocobaltite.[2]

Safety

Toxicity has rarely been observed. Animals, including humans, require trace amounts of cobalt, a component of vitamin B12.[1]

References

Шаблон:Reflist

External links

Шаблон:- Шаблон:Carbonates Шаблон:Cobalt compounds

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  1. ↑ 1,0 1,1 1,2 Шаблон:Ullmann
  2. ↑ 2,0 2,1 Шаблон:Cite web
  3. ↑ Шаблон:Cite journal
  4. ↑ Шаблон:Cite book
  5. ↑ G.A. El-Shobaky, A.S. Ahmad, A.N. Al-Noaimi and H.G. El-Shobaky Journal of Thermal Analysis and Calorimetry 1996, Volume 46, Number 6 , pp.1801-1808. online abstract
  6. ↑ Шаблон:Cite journal
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