Английская Википедия:Di-tert-butylcyclopentadiene
Di-tert-butylcyclopentadiene is an organic compound with the formula (Me3C)2C5H4, where Me = methyl. It is a colorless liquid that is soluble in organic solvents. The compound is the conjugate acid of the di-tert-butylcyclopentadienyl ligand, (Me3C)2C5H3−[1] (sometimes abbreviated Cp‡−). Two regioisomers of di-tert-butylcyclopentadiene exist, depending on the relative location of the double bonds.
Synthesis and reactions
Di-tert-butylcyclopentadiene is prepared by alkylation of cyclopentadiene with tert-butyl bromide under phase-transfer conditions.[2]
It is the precursor to many metal complexes, such as the olefin polymerization catalyst ((Me3C)2C5H3)TiCl3.[3]
The conjugate base of di-tert-butylcyclopentadiene reacts with a third equivalent of tert-butyl bromide to give (Me3C)3C5H3:
- (Me3C)2C5H4 + NaH → Na(Me3C)3C5H3 + H2
- Na(Me3C)2C5H3 + Me3CBr → (Me3C)3C5H3 + NaBr
References
