Английская Википедия:Dichloro(cycloocta-1,5-diene)platinum(II)
Материал из Онлайн справочника
Dichloro(1,5-cyclooctadiene)platinum(II) (Pt(cod)Cl2) is an organometallic compound of platinum. This colourless solid is an entry point to other platinum compounds through the displacement of the cod and/or chloride ligands. It is one of several complexes of cycloocta-1,5-diene.
Dichloro(1,5-cyclooctadiene)platinum(II) is prepared by treating potassium tetrachloroplatinate with the diene:[1]
- K2PtCl4 + C8H12 → PtCl2C8H12 + 2 KCl
According to X-ray crystallography, the complex is square planar.[2][3]
See also
References
Further reading
- J. L. Butikofer, E. W. Kalberer, W. C. Schuster, and D. M. Roddick, "The Crystal Structure of Dichloro(norbornadiene)platinum(II): A Comparison to Dichloro(cyclooctadiene)platinum(II)," Acta Crystallogr. C. 2004, m353-m354.