Английская Википедия:Dihydroimidazol-2-ylidene

Материал из Онлайн справочника
Версия от 10:39, 27 февраля 2024; EducationBot (обсуждение | вклад) (Новая страница: «{{Английская Википедия/Панель перехода}} {{Chembox | Watchedfields = changed | verifiedrevid = 430772414 | ImageFile = Dihydroimidazol-2-ylidene.png | ImageFile_Ref = {{chemboximage|correct|??}} | ImageSize = 121 | ImageName = Skeletal formula of dihydroimidazol-2-ylidene | PIN = Imidazolidin-2-ylidene |Section1={{Chembox Identifiers | ChemSpiderID = 11350507 | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | PubChe...»)
(разн.) ← Предыдущая версия | Текущая версия (разн.) | Следующая версия → (разн.)
Перейти к навигацииПерейти к поиску

Шаблон:Chembox

Dihydroimidazol-2-ylidene is a hypothetical organic compound with formula C3H6N2. It would be a heterocyclic compound, formally derived from imidazolidine with two hydrogen atoms removed from carbon number 2, leaving two vacant chemical bonds — which makes it a carbene.

Although carbenes in general are extremely short-lived, some derivatives of this compound are surprisingly stable, and form an important class of the persistent carbenes. They include the first stable carbenes postulated (but not isolated) by Hans-Werner Wanzlick around 1960.[1][2][3]

Файл:Wanzlick1.png
Wanzlick's mechanism for the reaction of dihydroimidazol-2-ylidene with electrophiles
Файл:SIMes.png
1,3-Dimesityl-imidazol-4,5-dihydro-2-ylidene, a stable carbene without delocalization around the ring containing the carbenic carbon
(external viewer)

They also include an example of the (saturated) imidazolin-2-ylidene (carbene) reported by A.J. Arduengo in 1995.[4]

References

Шаблон:Reflist

Шаблон:Heterocyclic-stub