Английская Википедия:Dithiofluorescein

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Версия от 22:24, 27 февраля 2024; EducationBot (обсуждение | вклад) (Новая страница: «{{Английская Википедия/Панель перехода}} {{Chembox |ImageFile = Dithiofluorescein.svg |IUPACName=3′,6′-Bis(sulfanyl)spiro[2-benzofuran-3,9′-xanthene]-1-one |OtherNames = {{ubl| * 3′,6′-Dimercaptofluoran<!-- saw 3',5' specifically mentioned in a PhD thesis, but seems inconsistent with typical syntheses of fluorans that would give more-symmetric patterns like 3',6' --> * 3′,6′-Dimercaptospiro[isobenzofuran-1(3''H'...»)
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Dithiofluorescein (sometimes generically called thiofluorescein) is a complexometric indicator used in analytical chemistry. It changes from blue to colorless when it binds to mercury(2+) ions.[1] It thus can indicate the endpoint in the titration of thiols using o-hydroxymercuribenzoic acid[2] or its sodium salt.[3] The reagent can be immobilized t in a polymer on a fiber optic, which might allow development of a detector for sulfide ions in a flow cell.[4] Unlike fluorescein and other related fluoran dyes that have oxygen substituents on the benzene rings, dithiofluorescein, which has sulfur substituents, is not fluorescent.[5]

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