Английская Википедия:Hexamethylcyclotrisiloxane

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Шаблон:Distinguish Шаблон:Chembox

Hexamethylcyclotrisiloxane, also known as D3 and D3, is the organosilicon compound with the formula Шаблон:Chem2. It is a colorless or white volatile solid. It finds limited use in organic chemistry. The larger tetrameric and pentameric siloxanes, respectively octamethylcyclotetrasiloxane and decamethylcyclopentasiloxane, are of significant industrial interest,[1] whereas 1,000–10,000 tonnes per year of the trimer is manufactured and/or imported in the European Economic Area.[2]

Structure and reactions

Hexamethylcyclotrisiloxane adopts a planar structure and is considered strained.[3][4] It reacts with organolithium reagents to give, after hydrolysis, dimethylsilanols:

Шаблон:Chem2
Шаблон:Chem2

Safety and environmental considerations

The LD50 for the related pentamer (D5) is >50 g/kg in rats.[1]

See also

References

Шаблон:Reflist