Английская Википедия:Hydronium perchlorate
Hydronium perchlorate is an inorganic chemical compound with the chemical formula Шаблон:Chem2. It is an unusual salt due to it being a solid and stable hydronium salt. It consists of hydronium cations Шаблон:Chem2 and perchlorate anions Шаблон:Chem2.
Production
Hydronium perchlorate is produced by the reaction of anhydrous perchloric acid and water in a 1:1 molar ratio:[1]
A more analytically reliable method was reported using the macrocyclic Schiff base of sodium 2,6-diformyl-4-methylphenolate and 2,6-diformyl-4-methylphenol as a chelating agent to sequester Cu(II): transmetallation of the macrocycle with copper(II) perchlorate yielded colorless crystals of hydronium perchlorate. [2]
It can also be produced by the reaction of anhydrous nitric acid and perchloric acid.[3]
References
Шаблон:Oxygen compounds Шаблон:Perchlorates
- ↑ Шаблон:Cite journal
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не указан текст - ↑ Шаблон:Cite book