Английская Википедия:Indane-1,2,3-trione

Материал из Онлайн справочника
Версия от 18:03, 25 марта 2024; EducationBot (обсуждение | вклад) (Новая страница: «{{Английская Википедия/Панель перехода}} {{chembox | Name = Indane-1,2,3-trione | ImageFile = Indantrione.svg | ImageSize = | IUPACName = Indane-1,2,3-trione | OtherNames = Indanetrione |Section1={{Chembox Identifiers | CASNo = 938-24-9 | ChemSpiderID = 63492 | EC_number = 213-340-1 | PubChem = 70309 | StdInChI=1S/C9H4O3/c10-7-5-3-1-2-4-6(5)8(11)9(7)12/h1-4H | StdInChIKey = WVZWEMOFSIEEMU-UHFFFAOYSA-N | SMILES2 = O=C2c1ccccc...»)
(разн.) ← Предыдущая версия | Текущая версия (разн.) | Следующая версия → (разн.)
Перейти к навигацииПерейти к поиску

Шаблон:Chembox Indane-1,2,3-trione is the organic compound with the formula C6H4(CO)3. The compound is the dehydrated derivative of C6H4(CO)2C(OH)2, known as ninhydrin, which is used to reveal fingerprints.

Indane-1,2,3-trione, which reacts readily with nucleophiles (including water). Whereas for most carbonyl compounds, a carbonyl form is more stable than a product of water addition (hydrate), ninhydrin forms a stable hydrate of the central carbon because of the destabilizing effect of the adjacent carbonyl groups.

To generate the ninhydrin chromophore (2-(1,3-dioxoindan-2-yl)iminoindane-1,3-dione), the amine must condense to give a Schiff base. The reaction of ninhydrin with secondary amines gives an iminium salt, which is also coloured, generally being yellow–orange.

References