Английская Википедия:Iridium(IV) oxide

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Версия от 23:21, 26 марта 2024; EducationBot (обсуждение | вклад) (Новая страница: «{{Английская Википедия/Панель перехода}} {{chembox | Verifiedfields = changed | Watchedfields = changed | verifiedrevid = 428744447 | ImageFile = Rutile-unit-cell-3D-balls.png | ImageSize = | IUPACName = | OtherNames = Iridium dioxide |Section1={{Chembox Identifiers | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID = 10605808 | InChI = 1/Ir.2O/q+4;2*-2 | InChIKey = NSTASKGZCMXIET-UHFFFAOYAQ | SMILES...»)
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Шаблон:Chembox Iridium(IV) oxide, IrO2, is the only well-characterised oxide of iridium. It is a blue-black solid. The compound adopts the TiO2 rutile structure, featuring six coordinate iridium and three coordinate oxygen.[1]

It is used with other rare oxides in the coating of anode-electrodes for industrial electrolysis and in microelectrodes for electrophysiology research.[2]

As described by its discoverers, it can be formed by treating the green form of iridium trichloride with oxygen at high temperatures:

2 IrCl3 + 2 O2 → 2 IrO2 + 3 Cl2

A hydrated form is also known.[3]

Application

Iridium dioxide can be used as an anode electrode for industrial electrolysis and as a microelectrode for electrophysiological studies.[4]

Iridium dioxide can be used to make coated electrodes.[5]

References

Шаблон:Reflist

Шаблон:Iridium compounds Шаблон:Oxygen compounds Шаблон:Authority control