Английская Википедия:Iron bis(diethyldithiocarbamate)
Iron bis(diethyldithiocarbamate) is a coordination complex with the formula Шаблон:Chem2 where Et = Шаблон:Chem2. A red solid, it is representative of several ferrous dithiocarbamates with diverse substituents in place of ethyl. In terms of structure, the species is dimeric, consisting of two pentacoordinate iron(II) centers. It is isostructural with Шаблон:Chem2, which in turn is similar to zinc bis(dimethyldithiocarbamate).[1]
Reactions
The complex reacts with a variety of reagents with concomitant formation of mono-iron derivatives. 9,10-Phenanthroline adds to iron bis(diethyldithiocarbamate) to give the blue-octahedral complex Шаблон:Chem2. 3,4-Bis(trifluoromethyl)-1,2-dithiete reacts to give the dithiolene complex Шаблон:Chem2.[2] Nitric oxide and carbon monoxide to give the nitrosyl complex Шаблон:Chem2 and the carbonyl complex Шаблон:Chem2, respectively.
Related compounds
References
