Английская Википедия:(Butadiene)iron tricarbonyl

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Шаблон:Chembox

(Butadiene)iron tricarbonyl is an organoiron compound with the formula (CШаблон:SubHШаблон:Sub)Fe(CO)Шаблон:Sub. It is a well-studied metal complex of butadiene.[1] An orange-colored viscous liquid that freezes just below room temperature, the compound adopts a piano stool structure.[2]

The complex was first prepared by heating iron pentacarbonyl with the diene.[3]

Related compounds

Iron(0) complexes of conjugated dienes have been extensively studied. In the butadiene series, (ηШаблон:Sup-CШаблон:SubHШаблон:Sub)Fe(CO)Шаблон:Sub and (ηШаблон:SupШаблон:Sup-CШаблон:SubHШаблон:Sub)(Fe(CO)Шаблон:Sub)Шаблон:Sub have been crystallized.[4] Many related complexes are known for substituted butadienes and related species. The species (ηШаблон:Sup-isoprene)iron tricarbonyl is chiral.[5]

See also

References

Шаблон:Reflist

External links

Шаблон:Iron compounds