Английская Википедия:Arsenide nitride
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Arsenide nitrides or nitride arsenides are compounds containing anions composed of nitride (N3−) and arsenide (As3−). They can be considered as mixed anion compounds or mixed pnictide compounds. Related compounds include the arsenide phosphides, germanide arsenides, arsenide carbides, and phosphide nitrides.
Arsenide and nitride are quite different in size, so alloys are challenging to produce.[1] They can be produced by heating an arsenide compound with a nitride, under pressure so that nitrogen does not escape.
List
name | formula | crystal
system |
space group | unit cell Å | volume | density | comment | ref |
---|---|---|---|---|---|---|---|---|
Mg3AsN | cubic | PmШаблон:Overbarm | a =4.2148 Z=1 | 74.88 | 3.589 | orange | [2] | |
Ca3AsN | orthorhombic | Pbnm | a=6.725 b=6.7198 c=9.5335 Z=4 | 430.8 | 3.237 | red; moisture sensitive | [3] | |
Ca14As6C0.445N1.135H4.915 | P4/mbm | a = 15.749 c = 9.1062 | red; band gap 1.6 eV | [4] | ||||
Cr3AsN | tetragonal | I4/mcm | a=5.360 c=8.066 | [5][6] | ||||
gallium arsenide nitride | Ga(As,N) | |||||||
indium gallium arsenide nitride | (In,Ga)(As,N) | |||||||
aluminium gallium arsenide nitride | (Al,Ga)(As,N) | |||||||
Sr3AsN | orthorhombic | Pbnm | a=7.1856 b=10.1446 c=7.1464 Z=4 | 520.93 | 4.486 | dark grey | [2] | |
Ba3AsN | orthorhombic | Pbnm | a=7.6741 b=10.7573 c=7.5387 Z=4 | 622.33 | 5.347 | black | [2] | |
LaFe2AsN | orthorhombic | Cmcm | a =3.79932 b =11.11461 c =7.18656 | 303.474 | [7] | |||
LaCo2AsN | orthorhombic | Cmcm | a =3.75993 b =11.1674 c =7.0185 | 294699 | [7] | |||
LaNi2AsN | orthorhombic | Cmcm | a =3.71584 b =11.4147 c =6.9786 | 296.004 | [7] | |||
Th2ONAs | PШаблон:Overbarm1 | a=4.041 c=6.979 | [8] | |||||
ThCrAsN | metallic | [9] | ||||||
ThMnAsN | tetragonal | P4/nmm | a =4.0818 b =4.0818 c =8.947 | metallic | [10] | |||
ThFeAsN | tetragonal | P4/nmm | a = 4.0367 c = 8.5262 | superconductor Tc 30 K | [11] | |||
ThFe1-xCoxAsN | superconductivity lost for x>0.05 | [12] | ||||||
ThNiAsN | tetragonal | P4/nmm | a=4,0804 c=7.9888 | superconductor at 4.3K | [13] | |||
BaTh2Fe4As4(N0.7O0.3)2 | a=3.9886 c=29.853 | Tc 22K | [14] | |||||
U2N2As | PШаблон:Overbarm1 | a=3.833 c=6.737 | [8] |
References
Шаблон:Nitrides Шаблон:Arsenides
- ↑ Шаблон:Cite book
- ↑ 2,0 2,1 2,2 Шаблон:Cite journal
- ↑ Шаблон:Cite journal
- ↑ Шаблон:Cite journal
- ↑ Шаблон:Cite journal
- ↑ Шаблон:Cite journal
- ↑ 7,0 7,1 7,2 Шаблон:Cite journal
- ↑ 8,0 8,1 Шаблон:Cite journal
- ↑ Шаблон:Cite journal
- ↑ Шаблон:Cite journal
- ↑ Шаблон:Cite journal
- ↑ Шаблон:Cite journal
- ↑ Шаблон:Cite journal
- ↑ Шаблон:Cite journal