Английская Википедия:Arsenide nitride

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Файл:Mg3AsN-ejic201900756-fig-0002-m.jpg
Cubic Mg3AsN, orthorhombic Ca3AsN Sr3AsN and Ba3AsN showing increased distortion as alkaline earth metal increases in size.

Arsenide nitrides or nitride arsenides are compounds containing anions composed of nitride (N3−) and arsenide (As3−). They can be considered as mixed anion compounds or mixed pnictide compounds. Related compounds include the arsenide phosphides, germanide arsenides, arsenide carbides, and phosphide nitrides.

Arsenide and nitride are quite different in size, so alloys are challenging to produce.[1] They can be produced by heating an arsenide compound with a nitride, under pressure so that nitrogen does not escape.

List

name formula crystal

system

space group unit cell Å volume density comment ref
Mg3AsN cubic PmШаблон:Overbarm a =4.2148 Z=1 74.88 3.589 orange [2]
Ca3AsN orthorhombic Pbnm a=6.725 b=6.7198 c=9.5335 Z=4 430.8 3.237 red; moisture sensitive [3]
Ca14As6C0.445N1.135H4.915 P4/mbm a = 15.749 c = 9.1062 red; band gap 1.6 eV [4]
Cr3AsN tetragonal I4/mcm a=5.360 c=8.066 [5][6]
gallium arsenide nitride Ga(As,N)
indium gallium arsenide nitride (In,Ga)(As,N)
aluminium gallium arsenide nitride (Al,Ga)(As,N)
Sr3AsN orthorhombic Pbnm a=7.1856 b=10.1446 c=7.1464 Z=4 520.93 4.486 dark grey [2]
Ba3AsN orthorhombic Pbnm a=7.6741 b=10.7573 c=7.5387 Z=4 622.33 5.347 black [2]
LaFe2AsN orthorhombic Cmcm a =3.79932 b =11.11461 c =7.18656 303.474 [7]
LaCo2AsN orthorhombic Cmcm a =3.75993 b =11.1674 c =7.0185 294699 [7]
LaNi2AsN orthorhombic Cmcm a =3.71584 b =11.4147 c =6.9786 296.004 [7]
Th2ONAs PШаблон:Overbarm1 a=4.041 c=6.979 [8]
ThCrAsN metallic [9]
ThMnAsN tetragonal P4/nmm a =4.0818 b =4.0818 c =8.947 metallic [10]
ThFeAsN tetragonal P4/nmm a = 4.0367 c = 8.5262 superconductor Tc 30 K [11]
ThFe1-xCoxAsN superconductivity lost for x>0.05 [12]
ThNiAsN tetragonal P4/nmm a=4,0804 c=7.9888 superconductor at 4.3K [13]
BaTh2Fe4As4(N0.7O0.3)2 a=3.9886 c=29.853 Tc 22K [14]
U2N2As PШаблон:Overbarm1 a=3.833 c=6.737 [8]

References

Шаблон:Reflist

Шаблон:Nitrides Шаблон:Arsenides