Английская Википедия:Azaborane

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Файл:Azaborane-3D-balls.png
Structure of closo-Шаблон:Chem2[1]

Azaborane usually refers a borane cluster where BH vertices are replaced by N or NR (R stands typically for H or organic substituent). Like many of the related boranes, these clusters are polyhedra and can be classified as closo-, nido-, arachno-, etc.

Within the context of Wade's rules, NR is a 4-electron vertex, and N is a 3-electron vertex. Prominent examples are the charge-neutral nido-Шаблон:Chem2 (i.e. Шаблон:Chem2) and closo-Шаблон:Chem2 (i.e. Шаблон:Chem2).[2]

Azaboranes can also refer to simpler compounds including iminoboranes (RB=NR', where R and R' stand typically for H or organic substituent) and borazines.

See also

References