Английская Википедия:Biosurfactant

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Biosurfactant usually refers to surfactants of microbial origin.[1] Most of the biosurfactants produced by microbes are synthesized extracellularly and many microbes are known to produce biosurfactants in large relative quantities.[2] Some are of commercial interest.[3] As a secondary metabolite of microorganisms, biosurfactants can be processed by the cultivation of biosurfactant producing microorganisms in the stationary phase on many sorts of low-priced substrates like biochar, plant oils, carbohydrates, wastes, etc. High-level production of biosurfactants can be controlled by regulation of environmental factors and growth circumstances. [4]

Classification

Biosurfactants are usually categorized by their molecular structure. Like synthetic surfactants, they are composed of a hydrophilic moiety made up of amino acids, peptides, (poly)saccharides, or sugar alcohols and a hydrophobic moiety consisting of fatty acids. Correspondingly, the significant classes of biosurfactants include glycolipids, lipopeptides and lipoproteins, and polymeric surfactants as well as particulate surfactants.[5]

Examples

Файл:1-Oleoyl-2-almitoyl-phosphatidylcholine Structural Formulae V.1.png
Phosphatidylcholine, also known as lecithin, is a pervasive biological surfactant. Shown in redcholine and phosphate group; blackglycerol; greenmonounsaturated fatty acid; bluesaturated fatty acid.

Common biosurfactants include:

  • Bile salts are mixtures of micelle-forming compounds that encapsulate food, enabling absorption through the small intestine.[6]
  • Lecithin, which can be obtained either from soybean or from egg yolk, is a common food ingredient.
  • Rhamnolipids, which can be produced by some species of Pseudomonas, e.g., Pseudomonas aeruginosa.[7]
  • Sophorolipids are produced by various nonpathogenic yeasts.
  • Emulsan produced by Acinetobacter calcoaceticus.[3]

Microbial biosurfactants are obtained by including immiscible liquids in the growth medium.[8]

Applications

Potential applications include herbicides and pesticides formulations, detergents, healthcare and cosmetics, pulp and paper, coal, textiles, ceramic processing and food industries, uranium ore-processing, and mechanical dewatering of peat.[8][1][2]

Oil spill remediation

Biosurfactants enhance the emulsification of hydrocarbons, thus they have the potential to solubilise hydrocarbon contaminants and increase their availability for microbial degradation.[9][10] In addition, biosurfactants can modify the cell surface of bacteria that biodegrade hydrocarbons, which can also increase the biodegradability of these pollutants to cells.[11] These compounds can also be used in enhanced oil recovery and may be considered for other potential applications in environmental protection.[12]

References

Шаблон:Reflist

External links

  1. 1,0 1,1 Шаблон:Cite journal
  2. 2,0 2,1 Шаблон:Cite journal
  3. 3,0 3,1 Шаблон:Cite journal
  4. Шаблон:Cite journal
  5. Шаблон:Cite journal
  6. Шаблон:Cite book
  7. Oliveira, F. J. S.; Vazquez, L.; de Campos, N. P.; de França, F. P., Production of rhamnolipids by a Pseudomonas alcaligenes strain. Process Biochemistry 2009, 44 (4), 383-389
  8. 8,0 8,1 Шаблон:Cite journal
  9. Шаблон:Cite journal
  10. Шаблон:Cite journal
  11. Шаблон:Cite journal
  12. Шаблон:Cite journal