Английская Википедия:Cyanate
Шаблон:Short description Шаблон:Distinguish
The cyanate ion is an anion with the chemical formula Шаблон:Chem2. It is a resonance of three forms: Шаблон:Chem2 (61%) ↔ Шаблон:Chem2 (30%) ↔ Шаблон:Chem2 (4%).
Cyanate is the derived anion of isocyanic acid, H−N=C=O, and its lesser tautomer cyanic acid (a.k.a. cyanol), H−O−C≡N.
Any salt containing the ion, such as ammonium cyanate, is called a cyanate.
The cyanate ion is an isomer of the much-less-stable fulminate anion, Шаблон:Chem2 or Шаблон:Chem2.[1]
The cyanate ion is an ambidentate ligand, forming complexes with a metal ion in which either the nitrogen or oxygen atom may be the electron-pair donor. It can also act as a bridging ligand.
Compounds that contain the cyanate functional group, −O−C≡N, are known as cyanates or cyanate esters. The cyanate functional group is distinct from the isocyanate functional group, −N=C=O; the fulminate functional group, Шаблон:Chem2; and the nitrile oxide functional group, Шаблон:Chem2 or Шаблон:Chem2.
Cyanate ion
The three atoms in a cyanate ion lie on a straight line, giving the ion a linear structure. The electronic structure is described most simply as
- :Ö̤−C≡N:
with a single C−O bond and a triple C≡N bond. (Or more completely as :Ö̤−C≡N: ↔ Ö̤=C=N̤̈ ↔ :O≡C−N̤̈:) The infrared spectrum of a cyanate salt has a band at ca. 2096 cm−1; such a high frequency is characteristic of a triple bond.[2]
The cyanate ion is a Lewis base. Both the oxygen and nitrogen atoms carry a lone pair of electrons and either one, the other, or both can be donated to Lewis acid acceptors. It can be described as an ambidentate ligand.
Cyanate salts
Sodium cyanate is isostructural with sodium fulminate, confirming the linear structure of the cyanate ion.[3] It is made industrially by heating a mixture of sodium carbonate and urea.[4]
A similar reaction is used to make potassium cyanate. Cyanates are produced when cyanides are oxidized. Use of this fact is made in cyanide decontamination processes where oxidants such as permanganate and hydrogen peroxide are used to convert toxic cyanide into less-toxic cyanate.
| Name | formula | Crystal system | Space group | Unit cell (Å) | volume (Å3) | Density (g/cm3) | Comment | Reference |
|---|---|---|---|---|---|---|---|---|
| Ammonium cyanate | NH4OCN | tetragonal | P4/nmm | a=5.082 b=5.082 c=5.551 | decomposes when heated to urea | [5] | ||
| Lithium cyanate | LiOCN | trigonal | RШаблон:Overlinem | a = 3.230 b = 14.268 Z=3 | 128.90 | 1.895 | melts at 475 °C | [6] |
| Sodium cyanate | NaOCN | hexagonal | RШаблон:Overlinem | a = 3.568 c = 15.123 | 166.72 | 1.94 | melts at 550 °C | [7] |
| Potassium cyanate | KOCN | tetragonal | I4/mcm | a = 6.091 c = 7.052 | 261.6 | 2.056 | melts at 315 °C | [8] |
| Rubidium cyanate | RbOCN | tetragonal | I4/mcm | a = 6.35 c = 7.38 | 297.58 | 2.85 | [9] | |
| Cesium cyanate | CsOCN | tetragonal | I4mcm | a = 6.519 c = 7.994 | 339.68 | 3.42 | [10] | |
| Thallium cyanate | TlOCN | tetragonal | I4mcm | a = 6.23 c = 7.32 | 284.3 | 5.76 | [9] | |
| Silver cyanate | AgOCN | monoclinic | P21/m | a = 5.474 b = 6.378 c = 3.417 β = 90.931° | 119.29 | 4.173 | melts at 652 °C | [11] |
| Strontium cyanate | Sr(OCN)2 | orthorhombic | Fddd | a = 6.151 b = 11.268 c = 11.848 Z = 8 | 821.1 | 2.78 | [12] |
Complexes with the cyanate ion
Cyanate is an ambidentate ligand which can donate the pair of electrons on the nitrogen atom or the oxygen atom, or both. Structurally the isomers can be distinguished by the geometry of the complex. In N-bonded cyanate complexes the M−NCO unit sometimes has a linear structure, but with O-bonded cyanate the M−O−C unit is bent. Thus, the silver cyanato complex, Шаблон:Chem2, has a linear structure as shown by X-ray crystallography.[13] However, the crystal structure of silver cyanate shows zigzag chains of nitrogen atoms and silver atoms.[14] There also exists a structure
NCO / \ Ni Ni \ / OCN
in which the Ni-N-C group is bent.[13]
Infrared spectroscopy has been used extensively to distinguish between isomers. Many complexes of divalent metals are N-bonded. O-Bonding has been suggested for complexes of the type Шаблон:Chem2, M = Mo(III), Re(IV), and Re(V). The yellow complex Шаблон:Chem2 and orange complex Шаблон:Chem2 are linkage isomers and show differences in their infrared spectra which can be used for diagnosis.[15]
The cyanate ion can bridge between two metal atoms by using both its donor atoms. For example, this structure is found in the compound Шаблон:Chem2. In this compound both the Ni−N−C unit and Ni−O−C unit are bent, even though in the first case donation is through the nitrogen atom.[16]
Cyanate functional group
Compounds that contain the cyanate functional group, −O−C≡N, are known as cyanates or cyanate esters. Aryl cyanates such are phenyl cyanate, Шаблон:Chem2 can be formed by a reaction of phenol with cyanogen chloride, ClCN, in the presence of a base.
Organic compounds that contain the isocyanate functional group −N=C=O are known as isocyanates. It is conventional in organic chemistry to write isocyanates with two double bonds, which accords with a simplistic valence bond theory of the bonding. In nucleophilic substitution reactions cyanate usually forms an isocyanate. Isocyanates are widely used in the manufacture of polyurethane[17] products and pesticides; methyl isocyanate, used to make pesticides, was a major factor in the Bhopal disaster.
See also
- Cyanide, Шаблон:Chem2 and nitrile group, −C≡N
- Isocyanide or isonitrile group, −N≡C
- Thiocyanate, Шаблон:Chem2, −S−C≡N
- Selenocyanate, Шаблон:Chem2, −Se−C≡N
- Tellurocyanate, Шаблон:Chem2, −Te−C≡N
- Isocyanate group, −N=C=O
- Isothiocyanate group, −N=C=S
- Isoselenocyanate group, −N=C=Se
References
External links
Bibliography
Шаблон:Cyanates Шаблон:Inorganic compounds of carbon Шаблон:Nitrogen compounds Шаблон:Functional groups
- ↑ William R. Martin and David W. Ball (2019): "Small organic fulminates as high-energy materials. Fulminates of acetylene, ethylene, and allene". Journal of Energetic Materials, volume 31, issue 7, pages 70-79. Шаблон:Doi
- ↑ Nakamoto, Part A, p171
- ↑ Wells, p722.
- ↑ Greenwood, p324
- ↑ Шаблон:Cite journal
- ↑ Шаблон:Cite journal
- ↑ Шаблон:Cite journal
- ↑ Шаблон:Cite journal
- ↑ 9,0 9,1 T. C. Waddington "Lattice parameters and infrared spectra of some inorganic cyanates" J. Chem. Soc., 1959, 2499-2502. Шаблон:Doi
- ↑ Шаблон:Cite journal
- ↑ Шаблон:Cite journal
- ↑ Шаблон:Cite journal
- ↑ 13,0 13,1 Шаблон:Greenwood&Earnshaw2nd (click here}
- ↑ Шаблон:Cite journal
- ↑ Nakamoto, Part B, pp 121–123.
- ↑ Greenwood, Table 8.9
- ↑ Шаблон:Cite journal
