Английская Википедия:Di-tert-butyl peroxide

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Шаблон:Short description

Шаблон:Chembox

Di-tert-butyl peroxide or DTBP is an organic compound consisting of a peroxide group bonded to two tert-butyl groups. It is one of the most stable organic peroxides, due to the tert-butyl groups being bulky. It is a colorless liquid.[1]

Reactions

The peroxide bond undergoes homolysis at temperatures above 100 °C. For this reason di-tert-butyl peroxide is commonly used as a radical initiator in organic synthesis and polymer chemistry. The decomposition reaction proceeds via the generation of methyl radicals.

(CH3)3COOC(CH3)3 → 2 (CH3)3CO
(CH3)3CO(CH3)2CO + Шаблон:Chem
2 Шаблон:ChemC2H6

DTBP can in principle be used in engines where oxygen is limited, since the molecule supplies both the oxidizer and the fuel.[2]

Toxicity

DTBP is an irritant to the nose, eyes, and skin. It is also flammable, so it should be handled with care.

See also

References

Шаблон:Reflist

External links