Английская Википедия:Di-tert-butylzinc

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Di-tert-butylzinc is a compound with the formula ZnC8H18. This compound is used as a meta activating reagent in the syntheses of N,N-dimethyl-3-iodoaniline from N,N-dimethylaniline.[1]

Synthesis

Di-tert-butylzinc is obtained from the reaction between tert-butyllithium and zinc chloride.[2]

2 (CH3)3CLi + ZnCl2 → Zn(C(CH3)3)2 + 2 LiCl

References

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