Английская Википедия:Diatomic carbon
Diatomic carbon (systematically named dicarbon and 1λ2,2λ2-ethene), is a green, gaseous inorganic chemical with the chemical formula C=C (also written [C2] or C2). It is kinetically unstable at ambient temperature and pressure, being removed through autopolymerisation. It occurs in carbon vapor, for example in electric arcs; in comets, stellar atmospheres, and the interstellar medium; and in blue hydrocarbon flames.[1] Diatomic carbon is the second simplest of the allotropes of carbon (after atomic carbon), and is an intermediate participator in the genesis of fullerenes.
Properties
C2 is a component of carbon vapor. One paper estimates that carbon vapor is around 28% diatomic,[2] but theoretically this depends on the temperature and pressure.
Electromagnetic properties
The electrons in diatomic carbon are distributed among the molecular orbitals according to the Aufbau principle to produce unique quantum states, with corresponding energy levels. The state with the lowest energy level, or ground state, is a singlet state (1ΣШаблон:Su), which is systematically named ethene-1,2-diylidene or dicarbon(0•). There are several excited singlet and triplet states that are relatively close in energy to the ground state, which form significant proportions of a sample of dicarbon under ambient conditions. When most of these excited states undergo photochemical relaxation, they emit in the infrared region of the electromagnetic spectrum. However, one state in particular emits in the green region. That state is a triplet state (3Πg), which is systematically named ethene-μ,μ-diyl-μ-ylidene or dicarbon(2•). In addition, there is an excited state somewhat further in energy from the ground state, which only form a significant proportion of a sample of dicarbon under mid-ultraviolet irradiation. Upon relaxation, this excited state fluoresces in the violet region and phosphoresces in the blue region. This state is also a singlet state (1Πg), which is also named ethene-μ,μ-diyl-μ-ylidene or dicarbon(2•).
State Excitation
enthalpy
(kJ mol−1)Relaxation
transitionRelaxation
wavelengthRelaxation EM-region X1ΣШаблон:Su 0 – – – a3ΠШаблон:Su 8.5 a3ΠШаблон:Su→X1ΣШаблон:Su 14.0 μm Long-wavelength infrared b3ΣШаблон:Su 77.0 b3ΣШаблон:Su→a3ΠШаблон:Su 1.7 μm Short-wavelength infrared A1ΠШаблон:Su 100.4 A1ΠШаблон:Su→X1ΣШаблон:Su
A1ΠШаблон:Su→b3ΣШаблон:Su1.2 μm
5.1 μmNear infrared
Mid-wavelength infraredB1ΣШаблон:Su ? B1ΣШаблон:Su→A1ΠШаблон:Su
B1ΣШаблон:Su→a3ΠШаблон:Su?
??
?c3ΣШаблон:Su 159.3 c3ΣШаблон:Su→b3ΣШаблон:Su
c3ΣШаблон:Su→X1ΣШаблон:Su
c3ΣШаблон:Su→B1ΣШаблон:Su1.5 μm
751.0 nm
?Short-wavelength infrared
Near infrared
?d3ΠШаблон:Su 239.5 d3ΠШаблон:Su→a3ΠШаблон:Su
d3ΠШаблон:Su→c3ΣШаблон:Su
d3ΠШаблон:Su→A1ΠШаблон:Su518.0 nm
1.5 μm
860.0 nmGreen
Short-wavelength infrared
Near infraredC1ΠШаблон:Su 409.9 C1ΠШаблон:Su→A1ΠШаблон:Su
C1ΠШаблон:Su→a3ΠШаблон:Su
C1ΠШаблон:Su→c3ΣШаблон:Su386.6 nm
298.0 nm
477.4 nmViolet
Mid-ultraviolet
Blue
Molecular orbital theory shows that there are two sets of paired electrons in a degenerate pi bonding set of orbitals. This gives a bond order of 2, meaning that there should exist a double bond between the two carbon atoms in a C2 molecule.[3] One analysis suggested instead that a quadruple bond exists,[4] an interpretation that was disputed.[5] CASSCF calculations indicate that the quadruple bond based on molecular orbital theory is also reasonable.[3] Bond dissociation energies (BDE) of B2, C2, and N2 show increasing BDE, indicating single, double, and triple bonds, respectively.
In certain forms of crystalline carbon, such as diamond and graphite, a saddle point or "hump" occurs at the bond site in the charge density. The triplet state of C2 does follow this trend. However, the singlet state of C2 acts more like silicon or germanium; that is, the charge density has a maximum at the bond site.[6]
Reactions
Diatomic carbon will react with acetone and acetaldehyde to produce acetylene by two different pathways.[2]
- Triplet C2 molecules will react through an intermolecular pathway, which is shown to exhibit diradical character. The intermediate for this pathway is the ethylene radical. Its abstraction is correlated with bond energies.[2]
- Singlet C2 molecules will react through an intramolecular, nonradical pathway in which two hydrogen atoms will be taken away from one molecule. The intermediate for this pathway is singlet vinylidene. The singlet reaction can happen through a 1,1-diabstraction or a 1,2-diabstraction. This reaction is insensitive to isotope substitution. The different abstractions are possibly due to the spatial orientations of the collisions rather than the bond energies.[2]
- Singlet C2 will also react with alkenes. Acetylene is a main product; however, it appears C2 will insert into carbon-hydrogen bonds.
- C2 is 2.5 times more likely to insert into a methyl group as into methylene groups.[7]
- There is a disputed possible room-temperature chemical synthesis via alkynyl-λ3-iodane.[8][9]
History
The light of gas rich comets mainly originates from the emission of diatomic carbon. An example is C/2014 Q2 (Lovejoy), where there are several lines of C2 light, mostly in the visible spectrum[10] , forming the Swan bands.[11] C/2022 E3 (ZTF), visible in early 2023, also exhibits green color due to the presence of diatomic carbon.[12]
See also
- Acetylide – a related chemical with the formula Шаблон:Chem
References
Шаблон:Allotropes of carbon Шаблон:Diatomic elements Шаблон:Molecules detected in outer space
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