Английская Википедия:Dichloro(cycloocta-1,5-diene)platinum(II)

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Dichloro(1,5-cyclooctadiene)platinum(II) (Pt(cod)Cl2) is an organometallic compound of platinum. This colourless solid is an entry point to other platinum compounds through the displacement of the cod and/or chloride ligands. It is one of several complexes of cycloocta-1,5-diene.

Dichloro(1,5-cyclooctadiene)platinum(II) is prepared by treating potassium tetrachloroplatinate with the diene:[1]

K2PtCl4 + C8H12 → PtCl2C8H12 + 2 KCl
Файл:PtCl2codStrem.jpg
Sample of Pt(cod)Cl2.

According to X-ray crystallography, the complex is square planar.[2][3]

See also

References

Further reading

  • J. L. Butikofer, E. W. Kalberer, W. C. Schuster, and D. M. Roddick, "The Crystal Structure of Dichloro(norbornadiene)platinum(II): A Comparison to Dichloro(cyclooctadiene)platinum(II)," Acta Crystallogr. C. 2004, m353-m354.

Шаблон:Platinum compounds