Английская Википедия:Dodecamethylcyclohexasilane

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Шаблон:Chembox

Dodecamethylcyclohexasilane is the organosilicon compound with the formula Шаблон:Chem2. It is one of the more readily prepared and easily handled polysilanes. Dodecamethylcyclohexasilane is produced by reduction of dimethyldichlorosilane with sodium-potassium alloy:[1]

Шаблон:Chem2

where M is Na or K. The reaction also produces a polymer poly(dimethylsilylene) Шаблон:Chem2 and a cyclic compound decamethylcyclopentasilane Шаблон:Chem2.

Шаблон:Gallery

The chair conformer of dodecamethylcyclohexasilane was confirmed by X-ray crystallography.[2][3]

Reactions

Dodecamethylcyclohexasilane reacts with potassium tert-butoxide to give the potassium derivative:[4]

Шаблон:Chem2

References