Английская Википедия:Georgiy B. Shul'pin

Материал из Онлайн справочника
Перейти к навигацииПерейти к поиску

Шаблон:Short description Georgiy Borisovich Shul’pin (Шаблон:Lang-ru, also Shulpin, 22 July 1946 – 3 March 2023) was born in Moscow, Russia. He graduated with a M.S. degree in chemistry from the Chemistry Department of Moscow State University in 1969. Between 1969 and 1972, he was a postgraduate student at the Nesmeyanov Institute of Organoelement Compounds (Academy of Sciences of the USSR, Moscow) under the direction of Prof. A. N. Nesmeyanov and received his Ph.D. in organometallic chemistry in 1975.[1] He received his Dr. of Sciences degree in 2013.

Career

Since 1978, Shul’pin has been working at the N. N. Semenov Institute of Chemical Physics at the Russian Academy of Sciences in Moscow. He is currently a senior scientific researcher. His research activities concern metal complex catalysis,[2] oxidation of hydrocarbons[3][4] particularly using “green oxidants” H2O2[5] and O2,[6] activation[7] and functionalization[8][9][10][11] of C–H bonds in saturated and aromatic hydrocarbons, organometallic chemistry. Other interests include photocatalysis,[12] biomimetic oxidations[13] and ecological chemistry.

In eighties Shul’pin together with A.E. Shilov discovered the metalation reaction of arenes by hexachloroplatinate which is stimulated by heating, light or gamma-irradiation[14][15][16][17][18][19][20] and affords stable sigma-aryl Pt(IV) complexes (“Shul’pin’s reaction”).[21]

He developed aerobic oxygenation of saturated hydrocarbons under visible light irradiation catalyzed by oxo and chloride complexes of transition metals[22] and discovered three efficient systems for the catalytic oxidations with hydrogen peroxide. Catalytic combinations: i) “vanadium derivative plus pyrazine-2-carboxylic acid (PCA)”;[23][24][25][26][27][28] ii) “a dinuclear manganese(IV) complex plus carboxylic acid”;[29][30] iii) “an osmium complex plus amine”.[31]

G. B. Shul’pin proposed a simple and convenient method for the estimation of concentration of alkyl hydroperoxides formed in alkane oxidations by molecular oxygen or peroxides. This method (gas-chromatographic analysis of the samples before and after their reduction by triphenylphosphine, “Shul’pin’s method”) is widely used in chemical practice.[32][33][34][35][36][37]

G. B. Shul’pin has published about 250 papers in chemical journals. He is the author (coauthor) of monographs[38][39][40][41] and reviews.[42][43][44][45][46] He has also written numerous books on popular science (for example,[47][48][49][50]) and articles in popular scientific journals.

References

Шаблон:Reflist

Шаблон:Authority control

Партнерские ресурсы
Криптовалюты
Магазины
Хостинг
Разное

  1. ↑ Шаблон:Cite book
  2. ↑ B. Plietker (Ed.), “Iron Catalysis in Organic Chemistry: Reactions and Applications”, WILEY-VCH, Weinheim, 2008, pp. 77, 80. Шаблон:ISBN
  3. ↑ Шаблон:Cite book
  4. ↑ R. H. Crabtree (Ed.), “Energy Production and Storage: Inorganic Chemical Strategies for a Warming World”, J. Wiley & Sons, Inc., Chichester, West Sussex, 2010. Chapter (pp. 101-142): B. G. Hashiguchi, C. H. Hövelmann, S. M. Bischof, K. S. Lokare, C. H. Leung, R. A. Periana, “Methane-to-Methanol Conversion”, pp. 11-113, 131, 134, 137. Шаблон:ISBN
  5. ↑ W. R. Sanderson, “Hydrogen Peroxide in Waste Minimisation – Current and Potential Contributions”, in: J. H. Clark, D. J. Macquarrie (Eds.), “Handbook of Green Chemistry and Technology”, Blackwell, Oxford, 2002, Chapter11, pp. 258-305. Шаблон:ISBN
  6. ↑ F. Cavani, S. Alini, “Synthesis of Adipic Acid: On the Way to More Sustainable Production”, Chapter 7 in: F. Cavani, G. Centi, S. Perathoner, F. Trifiró (Eds.), “Sustainable Industrial Chemistry”, WILEY-VCH, Weinheim, 2009. Шаблон:ISBN
  7. ↑ T. B. Gunnoe, “Metal-Mediated Carbon-Hydrogen Bond Activation”, Chapter 11 in: A. Bacac (Ed.), “Physical Inorganic chemistry: Reactions, Processes, and Applications”, J. Wiley & Sons, Inc., New Jersey, 2010, pp. 495-550. Шаблон:ISBN
  8. ↑ P. W. N. M. van Leeuwen, “Homogeneous Catalysis: Understanding the Art”, Kluwer, Dordrecht, 2004, Chapter 19 (“C-H Functionalization”). Шаблон:ISBN
  9. ↑ R. B. King, “Encyclopedia of Inorganic Chemistry: S”, Second Edition, J. Wiley & Sons, Inc., 2005, p. 4381. Шаблон:ISBN
  10. ↑ C.-J. Li, T.-H. Chan, “Comprehensive Organic Reactions in Aqueous Media”, J. Wiley & Sons, Inc., New Jersey, 2007, Шаблон:ISBN
  11. ↑ J.-Q. Yu, Z. Shi (Eds.), “C-H Activation”, Springer, Heidelberg, 2010. Шаблон:Doi
  12. ↑ T. Bitterwolf, “Photochemistry of Transition Metal Complexes”, in: “Encyclopedia of Inorganic Chemistry”, Wiley Online Library, 2006, Online Шаблон:ISBN Шаблон:Doi
  13. ↑ S. Tanase, E. Boluwman, “Selective Conversion of Hydrocarbons with H2O2 Using Biomimetic Non-heme Iron and Manganese Oxidation Catalysts”, in: R. Van Eldik, J. Reedijk (Eds.), “Adv. Inorg. Chem.: Homogeneous Biomimetic Oxidation Catalysis”, vol. 58, Academic Press, London, 2006, pp. 55, 63, 70. Шаблон:ISBN
  14. ↑ R. H. Crabtree, “The organometallic chemistry of alkanes”, Chem. Rev. 1985, 85, 245-269. Шаблон:Doi
  15. ↑ V. K. Jain, G. S. Rao, L. Jain, “The Organic Chemistry of Platinum(IV)”, in: “Advances in Organometallic Chemistry”, vol. 27, Academic Press, Inc., 1987, p. 116. Шаблон:ISBN
  16. ↑ G. K. Anderson, “Platinum-Carbon sigma-Bonded Complexes”, in: R. J. Puddephatt (Ed.), “Comprehensive Organometallic Chemistry II”, Elsevier, 1995, p. 518. Шаблон:ISBN
  17. ↑ L. Johansson, O. B. Ryan, C. Rømming, M. Tilset, “Unexpected Selectivities in C-H Activations of Toluene and p-Xylene at Cationic Platinum(II) Diimine Complexes.”, J. Am. Chem. Soc. 2001, 123, 6579-6590. Шаблон:Doi
  18. ↑ J. Mamtora, S. H. Crosby, C. P. Newman, G. J. Clarkson, J. P. Rourke, “Platinum(IV) Complexes: C-H Activation at Low Temperatures”, Organometallics 2008, 27, 5559–5565. Шаблон:Doi
  19. ↑ A. M. Voutchkova, R. H. Crabtree, J. Mol. Catal., A: Chem. 2009, 312, 1-6. Шаблон:Doi
  20. ↑ P. Sehnal, R. J. K. Taylor, I. J. S. Fairlamb, “Emergence of Palladium(IV) Chemistry in Synthesis and Catalysis”, Chem. Rev. 2010, 110, 824–889. Шаблон:Doi
  21. ↑ M. Ochiai, K. Fukui, S. Iwatsuki, K. Ishihara, K. Matsumoto, “Synthesis of aryl-platinum dinuclear complexes via ortho C-H bond activation of phenol and transmetalation of arylboronic acid”, Organometallics, 2005, 24, 5528-5536. Шаблон:Doi
  22. ↑ J.-E. Bäckvall (Ed.), “Modern Oxidation Methods”, WILEY-VCH Verlag, Weinheim, 2004, p. 121. Шаблон:ISBN http://www.wiley-vch.de/publish/en/books/bySubjectCH00/ISBN3-527-30642-0/?sID=8245b6d09961810d71a72151875fb5a1
  23. ↑ P. P. Knops-Gerrits, C. A. Trujillo, B. Z. Zhan, X. Y. Li, P. Rouxhet, P. A. Jacobs, “Oxidation catalysis with well-characterised vanadyl bis-bipyridine complexes encapsulated in NaY zeolite”, Topics in Catalysis, 1996, 437-449. Шаблон:Doi
  24. ↑ W. A. Herrmann (Ed.), “Synthetic Methods of Organometallic and Inorganic Chemistry: Catalysis (Herrmann/Brauer, vol. 10: Catalysis)”, Georg Thieme Verlag, Stuttgart, 2002, Chapter 10, pp. 117-121. Шаблон:ISBN
  25. ↑ G. A. Olah, A. Molnár, “Hydrocarbon Chemistry”, Second edition, J. Wiley & Sons, Inc., New Jersey, 2003, pp. 520 and 565. Шаблон:ISBN Шаблон:Doi http://www.wiley-vch.de/publish/en/books/bySubjectCH00/ISBN0-471-41782-3/?sID=8245b6d09961810d71a72151875fb5a1
  26. ↑ J.-E. Bäckvall (Ed.), “Modern Oxidation Methods”, WILEY-VCH Verlag, Weinheim, 2004, p. 121. Шаблон:ISBN
  27. ↑ R. Z. Khaliullin, A. T. Bell, M. Head-Gordon, “A Density Functional Theory Study of the Mechanism of Free Radical Generation in the System Vanadate/PCA/H2O2”, J. Phys. Chem. B 2005, 109, 17984-17992. Шаблон:Doi
  28. ↑ Z. Rappoport (Ed.), “The Chemistry of Peroxides”, J. Wiley & Sons, Inc., 2006, p. 1116. Шаблон:ISBN
  29. ↑ K. F. Sibbons, K. Shastri, M. Watkinson, “The application of manganese complexes of ligands derived from 1,4,7-triazacyclononane in oxidative catalysis (a review)”, Dalton Trans. 2006, 645-661. Шаблон:Doi
  30. ↑ “Alkanes: Webster’s Facts and Phrases”, ICON, San Diego, 2008, p. 41. Шаблон:ISBN
  31. ↑ G. A. Olah, A. Molnár, “Hydrocarbon Chemistry”, Second edition, J. Wiley & Sons, Inc., New Jersey, 2003, pp. 521 and 566. Шаблон:ISBN. Шаблон:Doi http://www.wiley-vch.de/publish/en/books/bySubjectCH00/ISBN0-471-41782-3/?sID=8245b6d09961810d71a72151875fb5a1
  32. ↑ Q. Yuan, W. Deng, Q. Zhang, Y. Wang, “Osmium-catalyzed selective oxidations of methane and ethane with hydrogen peroxide in aqueous medium”, Adv. Synth. Catal. 2007, 349, 1199–1209. Шаблон:Doi
  33. ↑ L. Zhou, Y. Chen, X. Yang, Y. Su, W. Zhang, J. Xu, “Electronic effect of substituent of quinones on their catalytic performance in hydrocarbons oxidation”, Catal. Let. 2008, 125, 154-159. Шаблон:Doi
  34. ↑ G. S. Mishra, T. F. S. Silva, L. M. D. R. S. Martins, A. J. L. Pombeiro,”Scorpionate complexes of vanadium(III or IV) as catalyst precursors for solvent-free cyclohexane oxidation with dioxygen”, Pure Appl. Chem., 2009, 81, 1217–1227. Шаблон:Doi
  35. ↑ K. T. Mahmudov, M. N. Kopylovich, M. F. C. G. da Silva, P. J. Figiel, Y. Y. Karabach, A. J. L. Pombeiro, “New copper(II) dimer and its catalytic activity in cyclohexane and benzyl alcohol oxidations”, J. Mol. Catal., A: Chem. 2010, 318, 44-50. Шаблон:Doi
  36. ↑ P. Roy, M. Manassero, “Tetranuclear copper(II)–Schiff-base complexes as active catalysts for oxidation of cyclohexane and toluene”, Dalton Trans. 2010, 1539-1545. Шаблон:Doi
  37. ↑ S. Bose, A. Pariyar, A. N. Biswas, P. Das, P. Bandyopadhyay, “Mild oxidation of hydrocarbons by tert-butyl hydroperoxide catalyzed by electron deficient manganese(III) corroles”, J. Mol. Catal., A: Chem. 2010, 332, 1-6 Шаблон:Doi.
  38. ↑ S. P. Gubin, G. B. Shul’pin, “The Chemistry of Complexes with Metal-Carbon Bonds”, Novosibirsk, Nauka, 1984, 280 pp. (in Russian).
  39. ↑ G. B. Shul’pin, “Organic Reactions Catalyzed by Metal Complexes”, Nauka, Moscow, 1988 (285 pp., in Russian). Шаблон:ISBN
  40. ↑ A. E. Shilov, G. B. Shul’pin, “Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes”, Kluwer Academic Publishers, Dordrecht/Boston/London, 2000, (548 pp.) (Springer, Шаблон:ISBN) https://www.springer.com/chemistry/physical+chemistry/book/978-0-7923-6101-5
  41. ↑ G. B. Shul’pin, “Oxidations of C–H Compounds Catalyzed by Metal Complexes”, in: "Transition Metals for Organic Synthesis", Eds. M. Beller, C. Bolm, Second Edition, WILEY-VCH Verlag, Weinheim, 2004, Vol. 2, Chapter 2.2, pp. 215–241. Шаблон:ISBN, Шаблон:ISBN
  42. ↑ A. E. Shilov, G. B. Shul’pin, “Activation of C–H Bonds by Metal Complexes”, Chem. Rev. 1997, 97(8), 2879–2932. Шаблон:Doi
  43. ↑ G. B. Shul’pin, "Metal-catalysed hydrocarbon oxygenations in solutions: the dramatic role of additives: a review", J. Mol. Catal. A: Chem. 2002, 189, 39–66. Шаблон:Doi
  44. ↑ G. B. Shul’pin, "Metal-catalysed hydrocarbon oxidations", Comptes Rendus, Chimie 2003, 6, 163–178. Шаблон:Doi
  45. ↑ G. B. Shul’pin, “Hydrocarbon Oxygenations with Peroxides Catalyzed by Metal Compounds”, Mini-Rev. Org. Chem. 2009, 6, 95–104.
  46. ↑ G. B. Shul’pin, “Selectivity enhancement in functionalization of C–H bonds: A review”, Org. Biomol. Chem. 2010, 8, 4217–4228. Шаблон:Doi
  47. ↑ G. B. Shul'pin, The World of Unusual Molecules: Organometallic Complexes, Moscow, Nauka, 1986, 176 pp. (in Russian).
  48. ↑ G. B. Shul'pin, Learning About Chemistry, Moscow, Mir Publishers, 1989, 232 pp. (in English). Шаблон:ISBN
  49. ↑ C. Shulpin, Que es la quimica organica, Ediciones Quinto Sol, Mexico, 1988, 272 pp. (in Spanish). Шаблон:ISBN
  50. ↑ G. B. Shulpin, Quimica para todos, Moscu, Editorial Mir, 1990, 264 pp. (in Spanish). Шаблон:ISBN
Источник — http://wikihandbk.com/ruwiki/index.php?title=Английская_Википедия:Georgiy_B._Shul%27pin&oldid=14912323