Английская Википедия:Hafnium tetrafluoride

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Шаблон:Chembox

Hafnium tetrafluoride is the inorganic compound with the formula HfF4. It is a white solid. It adopts the same structure as zirconium tetrafluoride, with 8-coordinate Hf(IV) centers.

Hafnium tetrafluoride forms a trihydrate, which has a polymeric structure consisting of octahedral Hf center, described as Шаблон:Chem2n(H2O)n and one water of crystallization. In a rare case where the chemistry of Hf and Zr differ, the trihydrate of zirconium(IV) fluoride has a molecular structure Шаблон:Chem2, without the lattice water.[1]

References

Шаблон:Reflist

Further reading

  • Benjamin, S. L., Levason, W., Pugh, D., Reid, G., Zhang, W., "Preparation and structures of coordination complexes of the very hard Lewis acids ZrF4 and HfF4", Dalton Transactions 2012, 41, 12548. Шаблон:Doi

Шаблон:Hafnium compounds Шаблон:Fluorine compounds

Шаблон:Inorganic-compound-stub