Английская Википедия:Iodate sulfate
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Iodate sulfates are mixed anion compounds that contain both iodate and sulfate anions. Iodate sulfates have been investigated as optical second harmonic generators, and for separation of rare earth elements.[1] Related compounds include the iodate selenates[2] and chromate iodates.[3]
Iodate sulfates can be produced from water solutions of iodic acid and sulfate salts.[4]
List
| formula | name | formula
weight |
system | space group | cell Å | volume | density | comments | ref |
|---|---|---|---|---|---|---|---|---|---|
| Na7(IO3)(SO4)3 | 624.01 | orthorhombic | P212121 | a=6.839 b=10.851 c=18.519 Z=4 | 1374.2 | 3.016 | at 100K; band gap 4.83; SHQ 0.5×KDP; birefringence 0.075 at 1064 nm | [5] | |
| Na9(IO3)(SO4)4 | Hectorfloresite | monoclinic | P21/a | a = 18.775 b = 6.9356 c = 14.239 β = 108.91° Z = 4 | [5][6] | ||||
| K2SO4·HIO3 | 350.17 | monoclinic | P21/n | a=7.4215 b=7.1578 c=13.802 β=93.330° Z=4 | 731.9 | 3.178 | colourless; birefingence 0.14 at 589.3 nm; UV edge 275 nm | [7] | |
| K3Na5Mg5(IO3)6(SO4)6(H2O)5 | trigonal | PШаблон:Overbarc1 | |||||||
| K7.2Na8.8Mg10(IO3)12(SO4)12(H2O)12 | Fuenzalidaite | trigonal | PШаблон:Overbarc1 | a = 9.4643 c = 27.336 | 2,120.52 | colourless; Uniaxial (-) nω = 1.622 nε = 1.615; Birefringence = 0.007 | [5][8][9] | ||
| Nb2O3(IO3)2(SO4) | 679.68 | monoclinic | P21 | a=5.299 b=20.479 c=5.452 β=119.095° Z=2 | 517.0 | 4.366 | band gap 3.25; SHG 6 × KDP; birefringence 0.22 at 1064 nm; stable below 580 °C | [5][10] | |
| Ce(IO3)2(SO4) | CISO | 585.98 | orthorhombic | P212121 | a=7.5366 b=8.9787 c=11.6121 Z=4 | 785.78 | 4.953 | yellow; SHG 3.5 × KDP; birefringence 0.259 at 546 nm | [11] |
| Sm(IO3)(SO4) | monoclinic | P21/c | a=9.3148 b=6.8678 c=8.2852 β=104.701° | [12] | |||||
| Sm2(IO3)3(SO4)OH·3H2O | triclinic | PШаблон:Overbar | a 7.3858 b 9.6166 c 11.8629 α=66.482° β=76.884° γ=69.101° | [12] | |||||
| Eu(IO3)(SO4) | monoclinic | P21/c | a=9.3083 b=6.8460 c=8.2575 β=104.696° | [5][1] | |||||
| Eu2(IO3)3(SO4)OH·3H2O | triclinic | PШаблон:Overbar | a=7.3666 b=9.5817 c=11.8263 α=66.5365° β=76.8591° γ=69.1131° | [12] | |||||
| Dy(IO3)(SO4)(H2O) | orthorhombic | P212121 | a=7.3088 b=9.4824 c=11.7302 α=66.6573° β=76.8745° γ=69.2970° | [5] | |||||
| Dy(IO3)(SO4)(H2O)3 | orthorhombic | P212121 | a=6.682 b=8.791 c=13.632 | [1] | |||||
| Dy2(IO3)3(SO4)OH·3H2O | triclinic | PШаблон:Overbar | [12] | ||||||
| Hg2(IO3)2(SO4) | monoclinic | C2/c | a=12.040 b=4.7133 c=15.533 β=102.43° | [13] | |||||
| Hg2(IO3)2(SO4)(H2O) | monoclinic | C2 | a=11.767 b=4.9190 c=7.8076 β=97.10° | band gap 3.98 eV; SHG 6 × KDP; dehydrate 250 °C | [13] | ||||
| Bi(IO3)(SO4) | 479.94 | monoclinic | P21/c | a=9.4355 b=6.9168 c=8.3374 β=105.168° Z=4 | 525.17 | 6.070 | band gap 3.91 eV; birefringence 0.087 at 1064 nm; colourless | [14] | |
| Bi2O(SO4)(IO3)2 | monoclinic | P21/n | a=7.2391 b=17.907 c=7.7964 β = 109.652° Z =4 | [4] | |||||
| AgBi(SO4)(IO3)2 | 1525.42 | triclinic | P1 | a=5.5189 b=6.9129 c=11.8527 α=90.598° β=92.151° γ=109.895° Z=1 | 424.78 | 5.963 | colourless; SHG 3.0 × KDP | [15] | |
| CdBi(IO3)(SO4)2 | 688.40 | monoclinic | P21/c | a=12.777 b=6.8491 c=9.984 β=103.23° Z=4 | 850.5 | 5.376 | band gap 4.03 eV; birefringence 0.100 at 1064 nm | [14] |
References
Шаблон:Iodates Шаблон:Sulfates
- ↑ 1,0 1,1 1,2 Шаблон:Cite journal
- ↑ Шаблон:Cite journal
- ↑ Шаблон:Cite journal
- ↑ 4,0 4,1 Шаблон:Cite journal
- ↑ 5,0 5,1 5,2 5,3 5,4 5,5 Шаблон:Cite journal
- ↑ Шаблон:Cite web
- ↑ Шаблон:Cite journal
- ↑ Шаблон:Cite web
- ↑ Шаблон:Cite web
- ↑ Шаблон:Cite journal
- ↑ Шаблон:Cite journal
- ↑ 12,0 12,1 12,2 12,3 Шаблон:Cite journal
- ↑ 13,0 13,1 Шаблон:Cite journal
- ↑ 14,0 14,1 Шаблон:Cite journal
- ↑ Шаблон:Cite journal
