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- | IUPACName = bis(2,3,4,5,6-pentafluorophenyl)xenon | ImageFile = Bis(pentafluorophenyl)xenon conformation.png ...6 Кб (812 слов) - 17:45, 9 февраля 2024
- ...doi=10.15227/orgsyn.059.0122}}</ref> Illustrative is preparation of [[tris(pentafluorophenyl)borane]]:<ref>Piers, W. E.; Chivers, T. “Pentafluorophenylboranes: from O ...edia|author1=Tanaka, Katsunori |author2=Fukase, Koichi|title=Lithium tetra(pentafluorophenyl)borate |encyclopedia=e-EROS Encyclopedia of Reagents for Organic Synthesis ...3 Кб (362 слова) - 04:15, 12 февраля 2024
- ...= Synthesis and Structure of the Dimethyl Sulfide Adducts of Mono- and Bis(pentafluorophenyl)borane | year = 2010 | last1 = Fuller | first1 = Anna-Marie | last2 = Hughe ...rapidly adds to the [[unsaturated bond]]s. The resulting [[organoborane]] compounds are useful [[Reaction intermediate|intermediates]] in [[organic synthesis]] ...7 Кб (839 слов) - 23:10, 10 февраля 2024
- ...cidity <ref>V. Gutmann, "Solvent effects on reactivities of organometallic compounds", ''Coord. Chem. Rev.'', 1976, '''18''', 225–255. [[doi: 10.1016/S0010-85 ...has been reviewed.<ref>I.B. Sivaev, V.L. Bregadze, "Lewis acidity of boron compounds", ''Coord. Chem. Rev.'', 2014, '''270/271''', 75-88. [[doi: 10.1016/j.ccr.2 ...8 Кб (1087 слов) - 18:24, 17 марта 2024
- ...hor6=Froehlich, R. |author7=Meyer, O. |title=Lewis Acid Properties of Tris(pentafluorophenyl)borane. Structure and Bonding in L-B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub ...rst2=Robert W. |date=1965-06-01 |title=The Ammonia and Alkylamine Addition Compounds of Carbon Monoxide Borane |url=http://dx.doi.org/10.1021/ja01089a009 |journ ...6 Кб (784 слова) - 23:10, 10 февраля 2024
- '''Aluminylenes''' are a sub-class of [[aluminium(I) compounds]] that feature singly-coordinated [[aluminium]] atoms with a [[lone pair]] ...]] elements, but the lower stability and higher reactivity of aluminium(I) compounds makes for interesting chemistry. The first aluminium(I) compound to be is ...17 Кб (2240 слов) - 22:47, 29 января 2024
- ...nyl amido complexes, although the definition goes far beyond this class of compounds. The term CGC is frequently used in connection with other more or less rela ...y reaction with [[co-catalyst]]s, e.g. [[methylaluminoxane]] (MAO), [[tris(pentafluorophenyl)borane]]s, and [[trityl]] borates. The catalytic systems based on CGCs, how ...5 Кб (676 слов) - 08:36, 21 февраля 2024
- Thus, a mixture of [[tricyclohexylphosphine]] (PCy<sub>3</sub>) and [[tris(pentafluorophenyl)borane]] reacts with hydrogen to give the respective [[phosphonium]] and [[ ...that a mixture of [[tricyclohexylphosphine]] (PCy<sub>3</sub>) and [[tris(pentafluorophenyl)borane]] reacts with H<sub>2</sub> to give the respective [[phosphonium]] a ...22 Кб (3042 слова) - 11:19, 10 марта 2024
- ...carbon-boron bond. The product of carboboration reactions are organoborane compounds which prove to be useful in [[organic synthesis]], containing both a new ca ...95 |title=l,l-Organoboration of alkynylsilicon, -germanium, -tin and -lead compounds |journal=Coordination Chemistry Reviews |volume=145 |page=125}}</ref> Howev ...18 Кб (2220 слов) - 01:07, 15 февраля 2024
- ...[[halogen]] [[iodine]] forms a number of stable [[Organic compound|organic compounds]], in which iodine exhibits higher [[Formal charge|formal]] [[Oxidation sta These iodine compounds are [[hypervalency|hypervalent]] because the iodine atom formally contains ...18 Кб (2359 слов) - 02:04, 24 марта 2024
- ...2=Autrey |first2=Tom |date=2012-10-18 |title=Boron–nitrogen–hydrogen (BNH) compounds: recent developments in hydrogen storage, applications in hydrogenation and [[File:C-F activation by B=P 2.png|thumb|444x444px|C-F activation of [[tris(pentafluorophenyl)borane]] by [(tmp)(L)B=PMes*] (L = IMe<sub>4</sub>)<ref name="Price-2017">{ ...31 Кб (4313 слов) - 06:01, 17 марта 2024
- ...=Evgeny |pages=1–33 |isbn=9780471238966 }}</ref> Many reactions of organic compounds with halogen involve autocatalytic radical [[reaction mechanism|mechanisms] ...s, Stuart Kauffman.</ref> Illustrative is the reaction amino adenosine and pentafluorophenyl ester in the presence of amino adenosine triacid ester (AATE). This experi ...11 Кб (1457 слов) - 11:04, 4 февраля 2024
- ==Compounds== ...or3=Taylor, Mark S. |title=Borinic Acids: A Neglected Class of Organoboron Compounds for Recognition of Diols in Aqueous Solution|journal=Australian Journal of ...26 Кб (3404 слова) - 00:07, 11 февраля 2024
- ...versus the other perhalobenzenes, resulting in lower aromaticity of those compounds compared to C<sub>6</sub>F<sub>6</sub>. ...irst3=R. |last4=Tatlow |first4=J. C. |date=1960 |title=Aromatic polyfluoro-compounds. Part VI. Penta- and 2,3,5,6-tetra-fluorothiophenol |journal=Journal of the ...14 Кб (1775 слов) - 07:00, 21 марта 2024
- ...rs.<ref>{{cite book |doi=10.1002/14356007.a19_545.pub2 |chapter=Phosphorus Compounds, Organic |title=Ullmann's Encyclopedia of Industrial Chemistry |year=2006 | ...ussRev>{{cite journal|title=Phosphine in the synthesis of organophosphorus compounds|first1=Boris A. |last1=Trofimov|first2=Svetlana N. |last2=Arbuzova|first3=N ...20 Кб (2469 слов) - 23:53, 23 марта 2024
- ...ore facile synthesis allowing a synthetic route to many low-valent gallium compounds. ...efits of Solid-State Analysis Aiding in the Synthesis of P→Ga Coordination Compounds|url=https://doi.org/10.1021/ic501139w|journal=Inorganic Chemistry|volume=53 ...35 Кб (4843 слова) - 06:55, 11 марта 2024
- ...um catalysts. A commonly used counter ion for borenium cations is tetrakis(pentafluorophenyl)borate, B(C<sub>6</sub>F<sub>5</sub>)<sub>4</sub><sup>−</sup>; however, o [[Category:Boron compounds]] ...27 Кб (3724 слова) - 23:11, 10 февраля 2024
- ...tuent. FITC reacts with the [[amine]] groups of many biologically relevant compounds including intracellular proteins to form a thiourea linkage. *Others: [[carboxyfluorescein]], [[carboxyfluorescein succinimidyl ester]], [[Pentafluorophenyl esters]] (PFP), [[tetrafluorophenyl esters]] (TFP) are other useful reagent ...26 Кб (3410 слов) - 11:56, 8 марта 2024
- ...s such as using high pressures and low temperatures, or employing chemical compounds that release H<sub>2</sub> upon demand. While large amounts of hydrogen are ...atalyzed [[hydrogenation|dehydrogenation reactions]]. Illustrative storage compounds are hydrocarbons, [[boron hydride]]s, [[Hydrogen storage#Ammonia|ammonia]], ...134 Кб (18 497 слов) - 23:42, 23 марта 2024
- ...ef>{{harvnb|Calvin|1969}}</ref>{{page needed|date=May 2022}} Some of these compounds like [[Hydrogen cyanide|hydrocyanic acid]] (HCN) have been proven in the ex ...sulfide and manganese sulfide in these ponds would have catalyzed organic compounds by abiotic photosynthesis.<ref>{{Cite journal |last1=Mulkidjanian |first1=A ...80 Кб (10 644 слова) - 21:36, 29 января 2024